Effect of ambient pressure on gas adsorption characteristics of residual coal in abandoned underground coal mines

2021 ◽  
Vol 90 ◽  
pp. 103900
Author(s):  
Xiangjun Chen ◽  
San Zhao ◽  
Liyang Li ◽  
Xinjian Li ◽  
Ningning Kang
Keyword(s):  
Gas Adsorption ◽  
Ambient Pressure ◽  
Coal Mines ◽  
Adsorption Characteristics ◽  
Underground Coal Mines ◽  
Residual Coal

Influence of intramolecular interactions on carbon dioxide gas adsorption capacity in Mesoporous Imine polymers

2018 ◽  
Author(s):  
Jaya Prakash Madda ◽  
Pilli Govindaiah ◽  
Sushant Kumar Jena ◽  
Sabbhavat Krishna ◽  
Rupak Kishor
Keyword(s):  
Carbon Dioxide ◽  
Adsorption Capacity ◽  
Density Functional ◽  
Gas Adsorption ◽  
Ambient Pressure ◽  
Condensation Reaction ◽  
Intramolecular Interactions ◽  
Carbon Dioxide Adsorption ◽  
Nitrogen Gas ◽  
Adsorption Characteristic

<p>Covalent organic Imine polymers with intrinsic meso-porosity were synthesized by condensation reaction between 4,4-diamino diphenyl methane and (para/meta/ortho)-phthaladehyde. Even though these polymers were synthesized from precursors of bis-bis covalent link mode, the bulk materials were micrometer size particles with intrinsic mesoporous enables nitrogen as well as carbon dioxide adsorption in the void spaces. These polymers were showed stability up to 260<sup>o</sup> centigrade. Nitrogen gas adsorption capacity up to 250 cc/g in the ambient pressure was observed with type III adsorption characteristic nature. Carbon dioxide adsorption experiments reveal the possible terminal amine functional group to carbamate with CO<sub>2</sub> gas molecule to the polymers. One of the imine polymers, COP-3 showed more carbon dioxide sorption capacity and isosteric heat of adsorption (Q<sub>st</sub>) than COP-1 and COP-2 at 273 K even though COP-3 had lower porosity for nitrogen gas than COP-1 and COP-2. We explained the trends in gas adsorption capacities and Qst values as a consequence of the intra molecular interactions confirmed by Density Functional Theory computational experiments on small molecular fragments.</p>

A new simple methodology for evaluation of explosion risk in underground coal mines

2013 ◽  
Vol 26 (6) ◽  
pp. 1524-1529 ◽  
Author(s):  
Ljiljana Medic Pejic ◽  
Javier García Torrent ◽  
Enrique Querol ◽  
Kazimierz Lebecki
Keyword(s):  
Coal Mines ◽  
Underground Coal Mines ◽  
Explosion Risk
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