Weibull statistics of the lap-shear strength developed at early stages of self-healing of the interfaces of glassy and semi-crystalline poly(ethylene terephthalate)

2020 ◽  
Vol 532 ◽  
pp. 119874 ◽  
Author(s):  
Yuri M. Boiko
2010 ◽  
Vol 654-656 ◽  
pp. 2632-2635
Author(s):  
Jun Lu ◽  
Dai Kun Xi ◽  
Rui Huang

In this study, the crystallization behaviors of the poly (ethylene terephthalate) oligomer/bisphenol-A polycarbonate (PETO/BAPC) blends were investigated under high pressure, and the recovered PETO/BAPC samples were characterized using XRD, DSC, SEM and AFM. The results showed that high-quality extended-chain single crystals with large c-axis thickness were formed in the multi-phase system within a relative short time, and the inner defects of the disclosed crystals could be removed by a self-healing process through high-temperature and high-pressure annealing. Morphologies of extended-chain crystals with different characteristics were also revealed with SEM and AFM. Wedge-shaped and bent extended-chain morphologies suggested that sliding diffusion and transesterification occurred simultaneously in the system, and the crystallization of the large crystals was a self-assembling process induced by chemical reactions at high pressure. This process provides a new route to grow large polymer extended-chain crystals and suggests self-assembly under high pressure is a promising method to create materials with new structures and properties.


2017 ◽  
Vol 5 (40) ◽  
pp. 21169-21177 ◽  
Author(s):  
J. Tang ◽  
L. Wan ◽  
Y. Zhou ◽  
H. Pan ◽  
F. Huang

The poly(1,2,3-triazolium) vitrimer adhesive has particularly high lap-shear strength (23.7 MPa) and can self-heal 20 times after being damaged.


2017 ◽  
Vol 07 (04) ◽  
pp. 218-226
Author(s):  
Wiranphat Thodsaratpreeyakul ◽  
Putinun Uawongsuwan ◽  
Akio Kataoka ◽  
Takanori Negoro ◽  
Hiroyuki Hamada

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