Addition reactions of CpRu(1-5-η-CH2CHCRCHSO2) (R = H, Me) with carbon monoxide, phosphorus, sulfur and nitrogen ligands: Spectroscopic and structural characterization of CpRu(1-2,5-η-butadienesulfonyl)(L)

We report herein on the synthesis and spectroscopic/crystallographic characterization of the first isolable, formally 16-electron Cp*Ru(κ2-P∼N) species, which are supported by N-phosphinoamidinate ligands. Despite the stability of such complexes, they have been shown to readily coordinate two-electron (L) donors including carbon monoxide and 2,6-xylylisocyanide, affording crystallographically characterized 18-electron Cp*Ru(L)(κ2-P∼N) adducts. Preliminary reactivity studies confirm that such complexes are capable of extruding hydrogen from ammonia borane.

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Diastereoselective Conjugate Addition Reactions of 2′-Hydroxypropiophenone to 2′-Hydroxychalcones – Synthesis and Structural Characterization of the Diastereomers of (±)-3-Aryl-1,5-bis(2-hydroxyphenyl)-2,4-dimethyl-1,5-pentanediones

European Journal of Organic Chemistry ◽

10.1002/(sici)1099-0690(199907)1999:7<1739::aid-ejoc1739>3.0.co;2-q ◽

1999 ◽

Vol 1999 (7) ◽

pp. 1739-1744 ◽

Cited By ~ 3

Author(s):

Artur M. S. Silva ◽

Lúcia M. P. M. Almeida ◽

Hilário R. Tavares ◽

José A. S. Cavaleiro

Keyword(s):

Structural Characterization ◽

Conjugate Addition ◽

Addition Reactions

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Reactions of the electronically unsaturated polyhydride tris[.mu.-bis(dimethylphosphino)methane]-.mu.-hydridotetrahydridodirhenium hexafluorophosphate with carbon monoxide and isocyanide ligands. Isolation and structural characterization of complexes of composition [Re2H5-nLn(.mu.-dmpm)3]PF6 (n = 2 or 4; L = CO or RNC)

Inorganic Chemistry ◽

10.1021/ic00048a010 ◽

1992 ◽

Vol 31 (22) ◽

pp. 4486-4491 ◽

Cited By ~ 5

Author(s):

Karen E. Meyer ◽

Phillip E. Fanwick ◽

Richard A. Walton

Keyword(s):

Carbon Monoxide ◽

Structural Characterization ◽

Isocyanide Ligands

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Synthesis and structural characterization of sulfur rich iron (II) carbonyl dimers: Facile reversible reaction with carbon monoxide

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2008.06.038 ◽

2009 ◽

Vol 694 (6) ◽

pp. 840-844 ◽

Cited By ~ 6

Author(s):

Inigo Aguirre de Carcer ◽

D. Michael Heinekey

Keyword(s):

Carbon Monoxide ◽

Structural Characterization ◽

Reversible Reaction

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Addition reactions of Cp*Ru(1-5-η-CH2CHCRCHSO2) (R = H, Me) with carbon monoxide, phosphorus, sulfur and nitrogen ligands: Spectroscopic and structural characterization of Cp*Ru(1-2,5-η-butadienesulfonyl)(L)

Structural characterization of a tetranuclear tungsten carbide cluster formed by the reductive cleavage of carbon monoxide: W4(μ4-C)(OCH2-c-C5H9)14

ChemInform Abstract: COPPER(I) COMPLEXES WITH UNSATURATED SMALL MOLECULES. PREPARATION AND STRUCTURAL CHARACTERIZATION OF COPPER(I)-DI-2-PYRIDYLAMINE COMPLEXES WITH OLEFINS, ACETYLENE, AND CARBON MONOXIDE

Site selectivity in carbon monoxide insertion into a PtC σ-bond of the binuclear complex [(CH3)ClPt(μ-Cl) (μ-Ph2PPy) Pt(CH3)(DMSO)]DMSO. Structural characterization of the derivatives [(CH3CO)ClPt(μ-Cl)(μ-Ph2 PPy)Pt(CH3)(DMSO)] and [(CH3)ClPt(μ-Ph2PPy)2Pt(COCH3)]+

Synthesis, characterization, and nucleophilic substitution-addition reactions of manganese-oxapentadienyl compounds. Structural characterization of [cyclic] (.eta.5-CH2CHCHCOCH3)Mn(CO)2L (L = CO, PPH3) and the first isolation of novel .eta.5-1-azapentadienyl complexes

ChemInform Abstract: REACTIONS OF RE2CL4(DPPM)2 WITH CARBON MONOXIDE THAT PROCEED WITH RETENTION OF THE METAL-METAL BOND: SYNTHESIS OF RE2CL4(DPPM)2(CO)N (N = 1, 2) AND THE STRUCTURAL CHARACTERIZATION OF CL2RE(μ-CL)(μ-CO)(μ-DPPM)2RECL(CO)

Spectroscopic, Redox, and Structural Characterization of the Ni-Labile and Nonlabile Forms of the Acetyl-CoA Synthase Active Site of Carbon Monoxide Dehydrogenase

Synthesis, structural characterization, and reactivity of Cp*Ru(N-phosphinoamidinate) complexes

Diastereoselective Conjugate Addition Reactions of 2′-Hydroxypropiophenone to 2′-Hydroxychalcones – Synthesis and Structural Characterization of the Diastereomers of (±)-3-Aryl-1,5-bis(2-hydroxyphenyl)-2,4-dimethyl-1,5-pentanediones

Synthesis and structural characterization of sulfur rich iron (II) carbonyl dimers: Facile reversible reaction with carbon monoxide

Addition reactions of CpRu(1-5-η-CH2CHCRCHSO2) (R = H, Me) with carbon monoxide, phosphorus, sulfur and nitrogen ligands: Spectroscopic and structural characterization of CpRu(1-2,5-η-butadienesulfonyl)(L)