Synthesis and structural characterization of sulfur rich iron (II) carbonyl dimers: Facile reversible reaction with carbon monoxide

2009 ◽  
Vol 694 (6) ◽  
pp. 840-844 ◽  
Author(s):  
Inigo Aguirre de Carcer ◽  
D. Michael Heinekey
Keyword(s):  
Carbon Monoxide ◽  
Structural Characterization ◽  
Reversible Reaction

Spectroscopic, Redox, and Structural Characterization of the Ni-Labile and Nonlabile Forms of the Acetyl-CoA Synthase Active Site of Carbon Monoxide Dehydrogenase

1998 ◽  
Vol 120 (30) ◽  
pp. 7502-7510 ◽  
Author(s):  
William K. Russell ◽  
Christina M. V. Stålhandske ◽  
Jinqiang Xia ◽  
Robert A. Scott ◽  
Paul A. Lindahl
Keyword(s):  
Carbon Monoxide ◽  
Structural Characterization ◽  
Active Site ◽  
Carbon Monoxide Dehydrogenase ◽  
Acetyl Coa

Synthesis, structural characterization, and reactivity of Cp*Ru(N-phosphinoamidinate) complexes

2014 ◽  
Vol 92 (3) ◽  
pp. 194-200 ◽  
Author(s):  
Colin M. Kelly ◽  
Adam J. Ruddy ◽  
Craig A. Wheaton ◽  
Orson L. Sydora ◽  
Brooke L. Small ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Structural Characterization ◽  
Ammonia Borane ◽  
The Stability

We report herein on the synthesis and spectroscopic/crystallographic characterization of the first isolable, formally 16-electron Cp*Ru(κ2-P∼N) species, which are supported by N-phosphinoamidinate ligands. Despite the stability of such complexes, they have been shown to readily coordinate two-electron (L) donors including carbon monoxide and 2,6-xylylisocyanide, affording crystallographically characterized 18-electron Cp*Ru(L)(κ2-P∼N) adducts. Preliminary reactivity studies confirm that such complexes are capable of extruding hydrogen from ammonia borane.

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