Chemical and radiation crosslinked polymer electrolyte membranes prepared from radiation-grafted ETFE films for DMFC applications

2006 ◽  
Vol 158 (1) ◽  
pp. 69-77 ◽  
Author(s):  
Jinhua Chen ◽  
Masaharu Asano ◽  
Tetsuya Yamaki ◽  
Masaru Yoshida
Keyword(s):  
Polymer Electrolyte ◽  
Polymer Electrolyte Membranes ◽  
Crosslinked Polymer ◽  
Electrolyte Membranes

Gradiently crosslinked polymer electrolyte membranes in fuel cells

2016 ◽  
Vol 301 ◽  
pp. 204-209 ◽  
Author(s):  
De An ◽  
Bin Wu ◽  
Genlei Zhang ◽  
Wen Zhang ◽  
Yuxin Wang
Keyword(s):  
Fuel Cells ◽  
Polymer Electrolyte ◽  
Polymer Electrolyte Membranes ◽  
Crosslinked Polymer ◽  
Electrolyte Membranes

Preparation of the crosslinked polymer electrolyte membranes based on a hyperbranched poly(amidoamine) and their proton conductivity

e-Polymers ◽  
2010 ◽  
Vol 10 (1) ◽  
Author(s):  
Yongwen Zhang ◽  
Wei Huang ◽  
Yongfeng Zhou ◽  
Deyue Yan
Keyword(s):  
Polymer Electrolyte ◽  
Proton Conductivity ◽  
Polymer Electrolyte Membranes ◽  
Crosslinked Polymer ◽  
Hyperbranched Poly ◽  
High Proton ◽  
Electrolyte Membranes ◽  
Potential Applications ◽  
Amine Groups ◽  
Transport Channels

AbstractA series of novel crosslinked polymer electrolyte membranes were successfully prepared based on the modification of a hyperbranched poly(amidoamine) with terminal vinyl groups. The membranes possessed the different contents of proton-generating sites (i.e., protonated tertiary amine groups) and triflate (Tf2N-) in the crosslinked network. They showed good mechanical and thermal stability. The water uptakes of them were ca. 8.4-24.5%. Their proton conductivity was of the order of ca. 10-5-10-2 S/cm in the range of 30-80 °C, and the proton conductivity increased with improving the protonation ratio. AFM results disclosed the micro-phase separation of the hydrophilic proton-generating sites and the hydrophobic domains of Tf2N- ions. The resulting locally continuous hydrophilic clusters could provide proton transport channels to produce the high proton conductivity. This kind of polymer electrolyte membranes may have potential applications in PEFCs and other electrochemical fields.

Proton conducting crosslinked polymer electrolyte membranes based on SBS block copolymer

2011 ◽  
Vol 121 (6) ◽  
pp. 3283-3291 ◽  
Author(s):  
Dong Kyu Roh ◽  
Jong Kwan Koh ◽  
Won Seok Chi ◽  
Yong Gun Shul ◽  
Jong Hak Kim
Keyword(s):  
Block Copolymer ◽  
Polymer Electrolyte ◽  
Polymer Electrolyte Membranes ◽  
Proton Conducting ◽  
Crosslinked Polymer ◽  
Electrolyte Membranes

Fuel-Cell Performance of Multiply-Crosslinked Polymer Electrolyte Membranes Prepared by Two-Step Radiation Technique

2019 ◽  
Vol 25 (1) ◽  
pp. 1439-1450 ◽  
Author(s):  
Tetsuya Yamaki ◽  
Shin-ichi Sawada ◽  
Masaharu Asano ◽  
Yasunari Maekawa ◽  
Masaru Yoshida ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Polymer Electrolyte ◽  
Polymer Electrolyte Membranes ◽  
Cell Performance ◽  
Fuel Cell Performance ◽  
Crosslinked Polymer ◽  
Electrolyte Membranes ◽  
Radiation Technique
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