scholarly journals Impact of electrode porosity architecture on electrochemical performances of 1 mm-thick LiFePO4 binder-free Li-ion electrodes fabricated by Spark Plasma Sintering

2021 ◽  
Vol 488 ◽  
pp. 229402
Author(s):  
Rakesh Elango ◽  
Arina Nadeina ◽  
François Cadiou ◽  
Vincent De Andrade ◽  
Arnaud Demortière ◽  
...  
Keyword(s):  
Spark Plasma Sintering ◽  
Electrochemical Performances ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
Binder Free ◽  
Li Ion

scholarly journals Thick Binder-Free Electrodes for Li-Ion Battery Fabricated Using Templating Approach and Spark Plasma Sintering Reveals High Areal Capacity

2018 ◽  
Vol 8 (15) ◽  
pp. 1703031 ◽  
Author(s):  
Rakesh Elango ◽  
Arnaud Demortière ◽  
Vincent De Andrade ◽  
Mathieu Morcrette ◽  
Vincent Seznec
Keyword(s):  
Spark Plasma Sintering ◽  
Li Ion Battery ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
Binder Free ◽  
Li Ion ◽  
Areal Capacity

Binder-free WC bulk synthesized by spark plasma sintering

2009 ◽  
Vol 479 (1-2) ◽  
pp. 427-431 ◽  
Author(s):  
Jiuxing Zhang ◽  
Guozhen Zhang ◽  
Shixian Zhao ◽  
Xiaoyan Song
Keyword(s):  
Spark Plasma Sintering ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
Binder Free

scholarly journals Mesoporous binder-free monoliths of few-walled carbon nanotubes by spark plasma sintering

2017 ◽  
Vol 53 (5) ◽  
pp. 3225-3238 ◽  
Author(s):  
Ch. Laurent ◽  
T. M. Dinh ◽  
M.-C. Barthélémy ◽  
G. Chevallier ◽  
A. Weibel
Keyword(s):  
Carbon Nanotubes ◽  
Spark Plasma Sintering ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
Binder Free ◽  
Walled Carbon Nanotubes

scholarly journals Electrical response of La2/3-xLi3xTiO3 ceramics obtained by spark plasma sintering

2020 ◽  
Vol 233 ◽  
pp. 04003
Author(s):  
J. Silva-Pereira ◽  
F. Guerrero ◽  
Y. Romaguera-Barcelay ◽  
L. Aguilera ◽  
R.S. Silva ◽  
...  
Keyword(s):  
Spark Plasma Sintering ◽  
Electrical Response ◽  
Complex Impedance ◽  
High Energy ◽  
Total Conductivity ◽  
Plasma Sintering ◽  
Interesting Candidate ◽  
Spark Plasma ◽  
Li Ion ◽  
Conductive Mechanism

The ceramic system La2/3-xLi3xTiO3 presents as an interesting candidate to be used as an electrolyte in solid-state Li-ion batteries. In this paper the electrical response of the ceramic, La2/3-xLi3xTiO3 with x = 0.11 is reported. La2/3-xLi3xTiO3 nanoparticles were synthesized by high energy milling and sintered by Spark Plasma Sintering from an amorphous phase. After sintering, the samples were structurally characterized by XRD and Raman techniques. Measurements of complex impedance varying frequency from 1 Hz to 10 MHz and temperature from 25 °C to 270 °C were performed. The study of DC conductivity allowed us to find the contributions to the total conductivity, grain, and grain boundary of the samples. From the activation energy values, it was possible to determine the conductive mechanism corresponding to the mobility of Li+ ions.

scholarly journals Spark Plasma Sintering of LiFePO4: AC Field Suppressing Lithium Migration

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2826
Author(s):  
Nan Luo ◽  
Yong Lin ◽  
Jian Guo ◽  
Emanuele Quattrocchi ◽  
Huaijiu Deng ◽  
...  
Keyword(s):  
Spark Plasma Sintering ◽  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
High Performance ◽  
Optical Emission ◽  
Ion Migration ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
Li Ion ◽  
Ac Field

Our work proposes a comparison between Spark Plasma Sintering of LiFePO4 carried out using an Alternating Current (AC) and Direct Current (DC). It quantifies the Li-ion migration using DC, and it validates such hypothesis using impedance spectroscopy, X-ray photoelectron spectroscopy and inductively coupled plasma optical emission spectroscopy. The use of an AC field seems effective to inhibit undesired Li-ion migration and achieve high ionic conductivity as high as 4.5 × 10−3 S/cm, which exceeds by one order of magnitude samples processed under a DC field. These results anticipate the possibility of fabricating a high-performance all-solid-state Li-ion battery by preventing undesired Li loss during SPS processing.

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