High resolution spectroscopic study of C2H4: Re-analysis of the ground state and , , , and vibrational bands

Author(s):  
O.N. Ulenikov ◽  
O.V. Gromova ◽  
Yu. S. Aslapovskaya ◽  
V.-M. Horneman
1957 ◽  
Vol 35 (6) ◽  
pp. 730-741 ◽  
Author(s):  
B. P. Stoicheff

The pure rotational lines and the Q branch lines of the 1–0 vibrational bands of H2, HD, and D2 have been photographed with a 21 ft. grating spectrograph. From these spectra, a complete set of constants for the ν = 0 and 1 levels of all three molecules have been determined. When these constants are combined with Herzberg's results of the forbidden infrared spectra of H2 and HD they lead to improved values of the electronic ground state constants of H2 and HD. The leading terms in the Dunham power series expansion of the potential are calculated for H2 and HD and are found to be mutually consistent. The isotopic relations are obeyed within experimental accuracy, and the small constants De, Be, and He, are in agreement with values given by theoretical formulae.


1985 ◽  
Vol 50 (11) ◽  
pp. 2480-2492 ◽  
Author(s):  
Soňa Přádná ◽  
Dušan Papoušek ◽  
Jyrki Kauppinen ◽  
Sergei P. Belov ◽  
Andrei F. Krupnov ◽  
...  

Fourier transform spectra of the ν2 band of PH3 have been remeasured with 0.0045 cm-1 resolution. Ground state combination differences from these data have been fitted simultaneously with the microwave and submillimeterwave data to determine the ground state spectroscopical parameters of PH3 including the parameters of the Δk = ± 3n interactions. The correlation between the latter parameters has been discussed from the point of view of the existence of two equivalent effective rotational operators which are related by a unitary transformation. The ΔJ = 0, +1, ΔK = 0 (A1 ↔ A2, E ↔ E) rotational transitions in the ν2 and ν4 states have been measured for the first time by using a microwave spectrometer and a radiofrequency spectrometer with acoustic detection.


2019 ◽  
Vol 32 ◽  
pp. 89-95 ◽  
Author(s):  
F.P. Condamine ◽  
E. Filippov ◽  
P. Angelo ◽  
S.A. Pikuz ◽  
O. Renner ◽  
...  

2011 ◽  
Vol 134 (23) ◽  
pp. 234306 ◽  
Author(s):  
Michael K. Bane ◽  
Evan G. Robertson ◽  
Christopher D. Thompson ◽  
Chris Medcraft ◽  
Dominique R. T. Appadoo ◽  
...  

1997 ◽  
Vol 92 (6) ◽  
pp. 1073-1082 ◽  
Author(s):  
By ZE-YI ZHOU ◽  
XIAO-GANG WANG ◽  
ZHONG-PING ZHOU ◽  
OLEG N. ULENIKOV ◽  
GALINA A. ONOPENKO ◽  
...  

1970 ◽  
Vol 239 (1) ◽  
pp. 42-56 ◽  
Author(s):  
H. W. Taylor ◽  
B. Singh ◽  
R. J. Cox ◽  
A. H. Kukoc

2012 ◽  
Vol 110 (17) ◽  
pp. 2063-2069 ◽  
Author(s):  
A. Baldacci ◽  
P. Stoppa ◽  
R. Visinoni ◽  
R. Wugt Larsen
Keyword(s):  

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