Coating of aluminum substrates with nanostructured Pd–Ni alloys by electrodeposition

2022 ◽  
Vol 277 ◽  
pp. 125524
Author(s):  
Fernando Meneses ◽  
Julieta S. Riva ◽  
Silvia E. Urreta ◽  
Paula G. Bercoff
Author(s):  
Anna C. Fraker

Small amounts of nickel are added to titanium to improve the crevice corrosion resistance but this results in an alloy which has sheet fabrication difficulties and is subject to the formation of large Ti2Ni precipitates. These large precipitates can serve as local corrosion sites; but in a smaller more widely dispersed form, they can have a beneficial effect on crevice corrosion resistance. The purpose of the present work is to show that the addition of a small amount of Mo to the Ti-1.5Ni alloy reduces the Ti2Ni precipitate size and produces a more elongated grained microstructure. It has recently been reported that small additions of Mo to Ti-0.8 to lw/o Ni alloys produce good crevice corrosion resistance and improved fabrication properties.


Author(s):  
G. M. Michal ◽  
T. K. Glasgow ◽  
T. J. Moore

Large additions of B to Fe-Ni alloys can lead to the formation of an amorphous structure, if the alloy is rapidly cooled from the liquid state to room temperature. Isothermal aging of such structures at elevated temperatures causes crystallization to occur. Commonly such crystallization pro ceeds by the nucleation and growth of spherulites which are spherical crystalline bodies of radiating crystal fibers. Spherulite features were found in the present study in a rapidly solidified alloy that was fully crysstalline as-cast. This alloy was part of a program to develop an austenitic steel for elevated temperature applications by strengthening it with TiB2. The alloy contained a relatively large percentage of B, not to induce an amorphous structure, but only as a consequence of trying to obtain a large volume fracture of TiB2 in the completely processed alloy. The observation of spherulitic features in this alloy is described herein. Utilization of the large range of useful magnifications obtainable in a modern TEM, when a suitably thinned foil is available, was a key element in this analysis.


Author(s):  
Matthew R. Libera

The liquid droplets produced by atomization processes are believed to undergo substantial supercooling during solidification, because the catalytic heterogeneities, for statistical reasons, tend to be isolated in the larger droplets. This supercooling can lead to the nucleation of metastable phases. As part of a study on the effect of liquid supercooling on nonequilibrium solidification, three binary Fe-Ni alloys have been produced by conventional argon atomization (Fe-20Ni, Fe-30Ni, and Fe-40Ni). The primary variables in these experiments are: i) the alloy composition; and ii) the powder particle diameter (inversely proportional to supercooling). Of particular interest in this system is the competitive nucleation kinetics between the stable fee and metastable bec phases. Bcc is expected to nucleate preferentially with decreasing %Ni and decreasing particle diameter.


2003 ◽  
Vol 112 ◽  
pp. 1043-1046 ◽  
Author(s):  
M. Nagasako ◽  
M. Nishida

2003 ◽  
Vol 112 ◽  
pp. 789-793 ◽  
Author(s):  
S. D. Prokoshkin ◽  
I. Yu. Khmelevskaya ◽  
V. Brailovski ◽  
F. Trochu ◽  
S. Turenne ◽  
...  

1982 ◽  
Vol 43 (C4) ◽  
pp. C4-535-C4-540
Author(s):  
R. Datta ◽  
V. Raghavan
Keyword(s):  

2011 ◽  
Vol 49 (01) ◽  
pp. 52-57 ◽  
Author(s):  
Min Kyu Paek ◽  
Kyung Hyo Do ◽  
Mohamed Bahgat ◽  
Jong Jin Pak

Author(s):  
Hayette Faid

AbstractIn this work, Zn-Ni alloys have been deposited on steel from sulfate bath, by electrodeposition method. The effect of Zn content on deposits properties was studied by cyclic voltammetry (CV), chronoaperometry (CA), linear stripping voltammetry (ALSV) and diffraction (XRD) and scanning electronic microscopy (SEM). The corrosion behavior in 3.5 wt. NaCl solution was examined using anodic polarization test and electrochemical impedance spectroscopy. X-ray diffraction of show that Zn-Ni alloys structure is composed of δ phase and γ phase, which increase with the decrease of Zn content in deposits. Results show that deposits obtained from bath less Zn2+ concentration exhibited better corrosion resistance.


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