4D evolution of Cr23C6 precipitates in neutron-irradiated and annealed HT-UPS steel observed via synchrotron micro-computed tomography

High-temperature-ultrafine precipitate strengthened (HT-UPS) steel is a potential structural material for advanced nuclear reactors; however, its irradiation response is not well understood. This research provides insight into irradiation-induced effects, such as precipitate evolution mechanisms and four-dimensional morphological evolution, in HT-UPS steel using synchrotron micro-computed tomography. Identical specimens were characterized pre-irradiation and post-irradiation following neutron exposure up to 0.3 displacements per atom at 600 °C. Irradiation effects were also differentiated from the annealing response of precipitates. Following neutron irradiation, the average Cr23C6 precipitate size reduced, affected by the synergy of nucleation and growth, ballistic dissolution, and inverse coarsening, which was observed at fluences an order of magnitude lower than previously observed. Annealing at 600 °C for 32 h increased the average Cr23C6 precipitate size and decreased the phase fraction, attributed to precipitate coarsening. The precipitate morphology evolution and resultant mechanisms can be utilized to parameterize and validate microstructural models simulating radiation damage or annealing. Graphical abstract

The size effect of martensite laths and precipitates on high strength wear-resistant steels

Low alloy high strength wear resistant steels are with high toughness, low cost and good abrasion resistance. It can effectively resist the propagation of wear cracks and prolong the service life of machine components. This paper focuses on the internal relationship between macroscopic physical properties and microscopic martensite lath and precipitate size throughout thickness of wear resistant steel. Four kinds of 40mm thickness wear resistant steels with different alloy chemical composition were produced and investigated. Results show the strength and hardness performance of ARIV are obviously higher than other three steels. ARI have a relatively large strength difference through thickness. The impact toughness of ARIV is relatively uniform, which is greater than that of the ARIII at middle layer and lower than that of the ARIII at 1/4 layer. The width of martensite lath of ARIV is relatively small, mainly 100 ~ 300 nm，while that of ARII and ARIII is mainly 200 ~400 nm. ARIV steel has shorter martensite lath band and more precipitates below 50 nm. It indicates that the size of martensite laths and precipitates of wear-resistant steels are important factors to determine its performance throughout thickness.

Impact of ionic composition of groundwater on oxidative iron precipitation

In the Netherlands, approximately 60% of drinking water is obtained from (generally anaerobic) groundwater. This requires aeration followed by rapid sand filtration (RSF) to remove iron, manganese, arsenic and ammonium. The mechanisms responsible for their removal or the clogging of RSFs and breakthrough of colloidal iron or manganese oxides have not been fully elucidated in previous studies. In this work, factors affecting iron precipitation have been studied in an aerated, continuously stirred bench scale jar experiments to simulate the supernatant layer of submerged sand filters. Time series data of filtered iron concentration and precipitate size have been collected in experiments with synthetic groundwater with and without P, Si, HCO3 and Ca at neutral pH. We show that precipitate growth is not influenced by different HCO3 concentrations but is reduced drastically when NOM is present and, to lesser extent, Si as well. The addition of P appears to hamper precipitate growth to some extent, but requires more research. We also observe that addition of Ca improves the growth of Fe precipitates in the presence of Si and especially NOM. These results have great significance for improving Fe removal efficiency of groundwater treatment plants in Netherlands and abroad.

Probability-Dependent Precipitation Strengthening Effect of Anisotropic Precipitate in Al-Mg-Si Alloy Produced by T6 Heat Treatment

This study proposed a constitutive equation to predict the change in yield strength according to the behavior of β″ metastable precipitates, which have a profound effect on strength among materials precipitated during the T6 heat treatment of Al-Mg-Si alloy. The β″ precipitate is a metastable phase before it becomes a β (Mg2Si) precipitate, and is distributed in the form of nano-scale rods in the aluminum alloy matrix. Existing precipitation strengthening models assume the shape of the precipitate to be spherical, and in that case the equation that depends on the Orowan mechanism with the average precipitate size and distribution should dominate. However, precipitates are formed in various shapes and sizes by anisotropic growth. In particular, rod-shaped precipitates are not suitable for the existing precipitation strengthening model. In this study, an Al-Mg-Si alloy was fabricated by gravity casting followed by T6 heat treatment. The new precipitation strengthening effect equation proposes that the β″ precipitate affects yield strength during plastic deformation of the Al-Mg-Si alloy. The proposed precipitation strengthening effect equation probabilistically considers the Critical Resolved Shear Stress (CRSS), which varies depending on the angle between the dislocation and the precipitate, when the dislocation passes through a rod-shaped precipitate.

Fatigue Crack Growth and Precipitation Characteristics of a High Zn-Containing Al-Zn-Mg-Cu Alloy with Various Typical Aging States

The fatigue crack growth of Al-Zn-Mg-Cu alloy can be adjusted by different aging treatments. In the present work, a high Zn-containing Al-Zn-Mg-Cu alloy was treated by single, double and triple stage aging treatments and typical T6, T79 and T77 states were selected by tensile properties. Fatigue crack growth under these aging states was tested and related fracture morphology and precipitation characteristics were observed. The results showed that fatigue crack growth resistance for the alloy was T6<T79<T77. The corresponding fracture morphology also showed the difference of fatigue striations and the measurement of them provided an additional evidence. The precipitation proved that the alloy with T6 state possessed GPI zone, GPII zone and η' phase while that for T76 state was GPII zone, η' phase and η phase. As for the T77 state, the precipitate types were GPII zone and η' phase. The matrix precipitate for T6 state was smaller and denser than that for T79 and T77 states while that for T77 state possessed a dense distribution than that for T79 state. The measurement of precipitate size distribution also proved it. The grain boundary precipitates for T79 and T77 states were similar, which had a more intermittent distribution than that for T6 state.

Turbine Blade Tip Repair by Laser Directed Energy Deposition Additive Manufacturing Using a Rene 142–MERL 72 Powder Blend

Laser directed energy deposition (LDED) was used with a powder blend comprising 75 wt.% Rene 142 and 25 wt.% of Merl 72 (4275M72) for turbine blade tip repair applications. Sound samples could be deposited at ambient temperature on Haynes 230. The microstructural analyses showed the presence of fine gamma prime precipitates in the as-deposited samples, while after aging, the alloy possessed around 40 vol.% with a bimodal precipitate size distribution. Also, the alloy contained Ta-Hf-W carbides in different sizes and shapes. Tensile testing from room temperature up to 1366 K was performed. The 4275M72 deposits possessed higher tensile properties compared to Rene 80 in this temperature range but lower elongations at the elevated temperatures. The creep properties of 4275M72 samples at 1255 K were superior to Rene 80. Also, the oxidation resistance of deposited 4275M72 was similar to Rene 142. The combination of high mechanical properties, creep behavior, and oxidation resistance of LDEDed 4275M72 makes it a suitable alloy for tip repair of turbine blades.

Characterization of Precipitation in 7055 Aluminum Alloy by Laser Ultrasonics

After different rolling conditions, four 7055 aluminum alloy samples with different precipitation sizes were measured by scanning electron microscope, transmission electron microscope and laser ultrasonic. The attenuation coefficients of ultrasound measured by laser ultrasonic were calculated in the time domain, frequency domain and wavelet denoising, respectively. The relationship between the precipitate size and attenuation coefficient was established. The results show that the attenuation of the ultrasonic wave is related to the size of the precipitated phase; this provides a new method for rapid non-destructive testing of the precipitation of aluminum alloys.