Facilitated transport graphene oxide based PPOdm mixed matrix membrane for CO2 separation

2018 ◽  
Vol 5 (10) ◽  
pp. 21818-21824 ◽  
Author(s):  
P.S. Murugiah ◽  
P.C. Oh ◽  
K.K. Lau
Keyword(s):  
Graphene Oxide ◽  
Facilitated Transport ◽  
Mixed Matrix Membrane ◽  
Co2 Separation ◽  
Mixed Matrix

scholarly journals POLYMERIC MIXED MATRIX MEMBRANES INCORPORATED WITH GRAPHENE OXIDE FOR H2/CO2 SEPARATION

2019 ◽  
Vol 81 (3) ◽  
Author(s):  
Rosiah Rohani ◽  
Hannaneh Milani Kalkhoran ◽  
Ying Tao Chung
Keyword(s):  
Contact Angle ◽  
Graphene Oxide ◽  
Fossil Fuels ◽  
Gas Permeability ◽  
Mixed Matrix Membranes ◽  
Inorganic Filler ◽  
Mixed Matrix Membrane ◽  
Co2 Separation ◽  
Mixed Matrix ◽  
Potential Alternative

Biohydrogen is a potential alternative for fossil fuels and it can be produced from POME fermentation. Membrane technology has been a prominent separation approach for H2 purification. However, membranes yield weakness in tradeoff between permeability and selectivity. The main objective of this project is to develop mixed matrix membrane with different polymeric bases of Polysulfone (PSF) and Polyimide (PI) with graphene oxide (GO) incorporation as inorganic filler for H2/CO2 separation. Gas permeability and selectivity results indicated that PI/GO membrane with 1 wt% of GO has the highest H2 and CO2 permeability at 501 GPU and 595 GPU at 1 bar, respectively, H2/CO2 selectivity of 1.01 at 5 bar and highest H2 purity of 83 %. FESEM analysis indicated changes in the pore size and top layer of membranes due to the presence of GO. Zeta potential analysis proved that PI/GO 1wt% membranes is highly negative-charged (-56 mV). Contact angle results showed a decrease in contact angle value with the addition of GO. It can be concluded that PI/GO 1 wt% membranes demonstrated better results in the aspects of permselectivity and physicochemical properties compared to PSF membranes.

In situ synthesis of polymer grafted ZIFs and application in mixed matrix membrane for CO2 separation

2018 ◽  
Vol 6 (7) ◽  
pp. 3151-3161 ◽  
Author(s):  
Yongqiang Gao ◽  
Zhihua Qiao ◽  
Song Zhao ◽  
Zhi Wang ◽  
Jixiao Wang
Keyword(s):  
Polymer Matrix ◽  
In Situ Synthesis ◽  
Mixed Matrix Membrane ◽  
Co2 Separation ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Interfacial Compatibility ◽  
Gas Separation Performance ◽  
Functionalized Surface

PEI-g-ZIF-8 presents appropriate porous structure, amino functionalized surface and improved interfacial compatibility with the polymer matrix to endow the MMMs with excellent gas separation performance.

Metal-organic framework/graphene oxide composite fillers in mixed-matrix membranes for CO2 separation

2018 ◽  
Vol 212 ◽  
pp. 513-522 ◽  
Author(s):  
Stavroula Anastasiou ◽  
Nidhika Bhoria ◽  
Jeewan Pokhrel ◽  
K. Suresh Kumar Reddy ◽  
C. Srinivasakannan ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Metal Organic Framework ◽  
Mixed Matrix Membranes ◽  
Co2 Separation ◽  
Mixed Matrix ◽  
Oxide Composite ◽  
Metal Organic ◽  
Organic Framework ◽  
Matrix Membranes
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