Engineering Nanocrystalline Titania Thin Films for High Photocatalytic Activity

2019 ◽  
Vol 9 ◽  
pp. 621-626 ◽  
Author(s):  
Vijila Kalarivalappil ◽  
Baiju K.Vijayan ◽  
Viswanathan Kumar
Keyword(s):  
Thin Films ◽  
Photocatalytic Activity ◽  
High Photocatalytic Activity ◽  
Nanocrystalline Titania

Photocatalytic Degradation of Humic Acid Using Fe3+ and N-Doped 3SnO2/TiO2 Thin Films Coated on Glass Fibers

2014 ◽  
Vol 608 ◽  
pp. 164-169
Author(s):  
Peerawas Kongsong ◽  
Lek Sikong ◽  
Sutham Niyomwas ◽  
Vishnu Rachpech
Keyword(s):  
Thin Films ◽  
Photocatalytic Activity ◽  
Humic Acid ◽  
Glass Fibers ◽  
Sol Gel ◽  
Composite Films ◽  
Dip Coating ◽  
High Photocatalytic Activity ◽  
Coating Methods ◽  
Uv Lamp

The Fe3+ and N–doped 3SnO2/TiO2 composite thin films and undoped films coated on glass fibers were prepared by sol–gel and dip–coating methods. The films were calcined at 600°C for 2 hour and characterized by XRD, SEM, EDS and XPS. The photocatalytic activity of the coated glass fibers was determined by means of degradation of a methylene blue (MB) solution and humic acid (HA). It was found that the optimized 20N/3SnO2/TiO2composite films exhibit a high photocatalytic activity and HA could be rapidly removed from water. The main factor affecting the HA degradation of 20N/3SnO2/TiO2 films is quantity of glass fibers loading, irradiation power of UV lamp and flow rate of water.

A facile solution approach to W,N co-doped TiO2 nanobelt thin films with high photocatalytic activity

2015 ◽  
Vol 3 (31) ◽  
pp. 15863-15868 ◽  
Author(s):  
Lu-Lu Lai ◽  
Jin-Ming Wu
Keyword(s):  
Thin Films ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
High Photocatalytic Activity ◽  
Light Illumination ◽  
Direct Oxidation ◽  
Solution Approach ◽  
Visible Light Illumination ◽  
Subsequent Calcination ◽  
Co Doped

W,N co-doped anatase TiO2 nanobelt films were synthesized by direct oxidation of metallic Ti substrates with H2O2 solutions containing H2WO4 and C3H6N6 at 80 °C, followed by a subsequent calcination. The photocatalytic activity of the W,N co-doped anatase TiO2 nanobelt films was nearly three times that of undoped alkali-hydrothermal synthesized anatase TiO2 nanobelt films, under UV and visible light illumination.

Photocatalytic activity, hydrophilic and optical properties of nanocrystalline titania thin films prepared by sol-gel dip coating

2011 ◽  
Vol 1352 ◽  
Author(s):  
M.C. Ferrara ◽  
L. Pilloni ◽  
A. Mevoli ◽  
S. Mazzarelli ◽  
L. Tapfer
Keyword(s):  
Thin Films ◽  
Optical Properties ◽  
Photocatalytic Activity ◽  
Sol Gel ◽  
Dip Coating ◽  
Fused Silica ◽  
Morphological Properties ◽  
Substrate Type ◽  
Nanocrystalline Titania ◽  
Anatase Titania

ABSTRACTNanocrystalline anatase titania thin films were prepared by using two different precursor solutions, a highly acid solution (Sol-1) and a polymer-like solution (Sol-2), via the dip-coating technique on different substrates (<100>-Si wafer, fused silica and soda lime glass). The influence of the two sol-gel titania precursor solutions and of the substrate type on the film morphology, coating porosity, surface roughness, crystalline phases and grain size of the titania films were investigated. Our experimental results clearly indicate that the sol - composition and substrate type remarkably influence the microstructural/morphological properties of the titanium dioxide. They consequently modify the optical response and hydrophilic performances of the samples. The photocatalytic oxidations of the methylene blue in water of the samples grown on the glass substrate were monitored to investigate the influence of the sol-gel precursor solution on the photocatalytic activity of the titania coatings, and the results were put in relation with the hydrophilic and optical properties of the films. The outcome demonstrates that the optical properties and the hydrophilic and photocatalytic performances of nanocrystalline titania can be opportunely tailored tuning the size dimension of the crystalline domain according to the specific coating applications.

Photocatalytic degradation of methylene blue from aqueous solutions using nanopillars-TiO2 thin films: Batch reactor studies

2018 ◽  
Vol 18 (3) ◽  
pp. 81-91 ◽  
Author(s):  
C. Lalhriatpuia
Keyword(s):  
Thin Films ◽  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Organic Carbon ◽  
Photocatalytic Degradation ◽  
Batch Reactor ◽  
Tio2 Thin Films ◽  
Initial Concentration ◽  
Bet Specific Surface Area ◽  
Interfering Ions

Nanopillars-TiO2 thin films was obtained on a borosilicate glass substrate with (S1) and without (S2) polyethylene glycol as template. The photocatalytic behaviour of S1 and S2 thin films was assessed inthe degradation of methylene blue (MB) dye from aqueous solution under batch reactor operations. The thin films were characterized by the SEM, XRD, FTIR and AFM analytical methods. BET specific surface area and pore sizes were also obtained. The XRD data confirmed that the TiO2 particles are in its anatase mineral phase. The SEM and AFM images indicated the catalyst is composed with nanosized pillars of TiO2, evenly distributed on the surface of the substrate. The BET specific surface area and pore sizes of S1 and S2 catalyst were found to be 5.217 and 1.420 m2/g and 7.77 and 4.16 nm respectively. The photocatalytic degradation of MB was well studied at wide range of physico-chemical parameters. The effect of solution pH (pH 4.0 to 10.0) and MB initial concentration (1.0 to 10.0 mg/L) was extensively studied and the effect of several interfering ions, i.e., cadmium nitrate, copper sulfate, zinc chloride, sodium chloride, sodium nitrate, sodium nitrite, glycine, oxalic acid and EDTA in the photocatalytic degradation of MB was demonstrated. The maximum percent removal of MB was observed at pH 8.0 beyond which it started decreasing and a low initial concentration of the pollutant highly favoured the photocatalytic degradation using thin films and the presence of several interfering ions diminished the photocatalytic activity of thin films to some extent. The overall photocatalytic activity was in the order: S2 > S1 > UV. The photocatalytic degradation of MB was followed the pseudo-first-order rate kinetics. The mineralization of MB was studied with total organic carbon measurement using the TOC (total organic carbon) analysis.

STRUCTURAL, OPTICAL PROPERTIES AND PHOTOCATALYTIC ACTIVITY OF NANOCRYSTALLINE TiO2 THIN FILMS DEPOSITED BY SOL-GEL SPIN COATING

2019 ◽  
Vol 7 (1) ◽  
pp. 28
Author(s):  
KOMARAIAH DURGAM ◽  
RADHA EPPA ◽  
REDDY M. V. RAMANA ◽  
KUMAR J. SIVA ◽  
R. SAYANNA ◽  
...  
Keyword(s):  
Thin Films ◽  
Optical Properties ◽  
Photocatalytic Activity ◽  
Spin Coating ◽  
Sol Gel ◽  
Tio2 Thin Films ◽  
Nanocrystalline Tio2

Use of Nanopillars-TiO2 Thin Films in the Photocatalytic Degradation of Bromophenol Blue from Aqueous Solution

2018 ◽  
Vol 6 (1) ◽  
pp. 22-30
Author(s):  
C. Lalhriatpuia ◽  
◽  
Thanhming liana ◽  
K. Vanlaldinpuia
Keyword(s):  
Thin Films ◽  
Aqueous Solution ◽  
Photocatalytic Activity ◽  
Photocatalytic Degradation ◽  
Batch Reactor ◽  
Bromophenol Blue ◽  
Tio2 Thin Films ◽  
Initial Concentration ◽  
Bet Specific Surface Area ◽  
Interfering Ions

The photocatalytic activity of Nanopillars-TiO2 thin films was assessed in the degradation of Bromophenol blue (BPB) dye from aqueous solution under batch reactor operations. The thin films were characterized by the XRD, SEM and AFM analytical methods. BET specific surface area and pore sizes were also obtained. The XRD data showed anatase phase of TiO2 particles with average particle size of 25.4 and 21.9 nm, for S1 and S2 catalysts respectively. The SEM and AFM images indicated the catalyst composed with Nanosized pillars of TiO2, evenly distributed on the surface of the substrate. The average height of the pillars was found to be 180 and 40 nm respectively for the S1 and S2 catalyst. The BET specific surface area and pore sizes of S1 and S2 catalyst were found to be 5.217 and 1.420 m2/g and 7.77 and 4.16 nm respectively. The photocatalytic degradation of BPB using the UV light was studied at wide range of physico-chemical parametric studies to determine the mechanism of degradation as well as the practical applicability of the technique. The batch reactor operations were conducted at varied pH (pH 4.0 to 10.0), BPB initial concentration (1.0 to 20.0 mg/L) and presence of several interfering ions, i.e., cadmium nitrate, copper sulfate, zinc chloride, sodium chloride, sodium nitrate, sodium nitrite, glycine, oxalic acid and EDTA in the photocatalytic degradation of BPB. The maximum percent removal of BPB was observed at pH 6.0 and a low initial concentration of the pollutant highly favours the photocatalytic degradation using thin films. The presence of several interfering ions suppressed the photocatalytic activity of thin films to some extent. The time dependence photocatalytic degradation of BPB was demonstrated with the pseudo-first-order rate kinetics. Study was further extended with total organic carbon measurement using the TOC (Total Organic Carbon) analysis. This demonstrated an apparent mineralization of BPB from aqueous solutions.

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