scholarly journals Unprecedented scaling/fouling resistance of omniphobic polyvinylidene fluoride membrane with silica nanoparticle coated micropillars in direct contact membrane distillation

2020 ◽  
Vol 599 ◽  
pp. 117819 ◽  
Author(s):  
Zechun Xiao ◽  
Hong Guo ◽  
Hailong He ◽  
Yongjie Liu ◽  
Xuemei Li ◽  
...  
Keyword(s):  
Direct Contact ◽  
Polyvinylidene Fluoride ◽  
Silica Nanoparticle ◽  
Membrane Distillation ◽  
Fouling Resistance ◽  
Direct Contact Membrane Distillation

Characteristic and Performance of Polyvinylidene Fluoride Membranes Blended with Lithium Chloride in Direct Contact Membrane Distillation

2014 ◽  
Vol 69 (9) ◽  
Author(s):  
S. O. Lai ◽  
K. C. Chong ◽  
K. M. Lee ◽  
W. J. Lau ◽  
B. S. Ooi
Keyword(s):  
Lithium Chloride ◽  
Direct Contact ◽  
Polyvinylidene Fluoride ◽  
Membrane Separation ◽  
Polymeric Materials ◽  
Membrane Distillation ◽  
Inversion Method ◽  
Permeate Flux ◽  
Separation Processes ◽  
Direct Contact Membrane Distillation

Membrane distillation (MD) is one of the recent rising membrane separation techniques adopted in the desalination and wastewater treatment. Unlike other pressure-driven separation processes such as reverse osmosis and nanofiltration, MD is a thermal-driven process which involves vapor pressure difference across the feed and permeates solutions. As such, MD requires low energy consumption. Hydrophobic polymeric materials such as polyvinylidene fluoride (PVDF) are frequently used in direct contact membrane distillation (DCMD) due to low surface energy and promising thermal resistance. In this study, the DCMD hollow fiber membranes were separately prepared with PVDF and PVDF blended with lithium chloride (LiCl) through dry/wet phase inversion method. Subsequently, the membranes were used in a DCMD process to remove sodium chloride (NaCl) under different feed inlet temperatures to examine the effect of LiCl additives on the neat membrane. The result showed that by adding LiCl into the neat membrane solution, the finger-like structure was change to a sponge-like structure with microvoids. Furthermore, the performance of the LiCl additive membrane in term of permeate flux was found to be 20% higher compared to that of the neat membrane. Other results of the membrane characteristics were also discussed.      

Performance evaluation of ePTFE and PVDF flat-sheet module direct contact membrane distillation

2010 ◽  
Vol 62 (2) ◽  
pp. 347-352 ◽  
Author(s):  
Ching-Jung Chuang ◽  
Kuo-Lun Tung ◽  
Yang-Hsiang Fan ◽  
Chii-Dong Ho ◽  
James Huang
Keyword(s):  
Direct Contact ◽  
Polyvinylidene Fluoride ◽  
Membrane Distillation ◽  
Membrane Properties ◽  
Energy Integration ◽  
Permeate Flux ◽  
Increase Energy Efficiency ◽  
Module Design ◽  
Direct Contact Membrane Distillation ◽  
Flat Sheet

This paper reports experiments using a flat-sheet module with 0.18 ∼ 0.45 μm ePTFE (expanded polytetrafluoroethylene) and PVDF (polyvinylidene fluoride) membranes to show the effects of membrane properties, salt concentration and fluid hydrodynamics on the permeate flux and salt rejection of DCMD (direct contact membrane distillation). A theoretical prediction of the permeate flux was carried out, and was in close agreement with the experimental results. In addition, the energy integration of the process was also analyzed in order to evaluate module design to increase energy efficiency. According to the simulated results of the energy integration design, a combination of simultaneous cooling of the permeate stream and an additional heat exchanger to lower the temperature of the permeate stream not only enhances the MD flux, but also reduces energy consumption.

scholarly journals Porous Hydrophobic–Hydrophilic Composite Hollow Fiber and Flat Membranes Prepared by Plasma Polymerization for Direct Contact Membrane Distillation

Membranes ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 120 ◽  
Author(s):  
Ashok K. Sharma ◽  
Adam Juelfs ◽  
Connor Colling ◽  
Saket Sharma ◽  
Stephen P. Conover ◽  
...  
Keyword(s):  
Hollow Fiber ◽  
Direct Contact ◽  
Plasma Polymerization ◽  
Polyvinylidene Fluoride ◽  
Hydrophobic Surface ◽  
Diffusion Path ◽  
High Water ◽  
Membrane Distillation ◽  
Vapor Flux ◽  
Direct Contact Membrane Distillation

High water vapor flux at low brine temperatures without surface fouling is needed in membrane distillation-based desalination. Brine crossflow over surface-modified hydrophobic hollow fiber membranes (HFMs) yielded fouling-free operation with supersaturated solutions of scaling salts and their precipitates. Surface modification involved an ultrathin porous polyfluorosiloxane or polysiloxane coating deposited on the outside of porous polypropylene (PP) HFMs by plasma polymerization. The outside of hydrophilic MicroPES HFMs of polyethersulfone was also coated by an ultrathin coating of porous plasma-polymerized polyfluorosiloxane or polysiloxane rendering the surface hydrophobic. Direct contact membrane distillation-based desalination performances of these HFMs were determined and compared with porous PP-based HFMs. Salt concentrations of 1, 10, and 20 wt% were used. Leak rates were determined at low pressures. Surface and cross-sections of two kinds of coated HFMs were investigated by scanning electron microscopy. The HFMs based on water-wetted MicroPES substrate offered a very thin gas gap in the hydrophobic surface coating yielding a high flux of 26.4–27.6 kg/m2-h with 1 wt% feed brine at 70 °C. The fluxes of HFMs on porous PP substrates having a long vapor diffusion path were significantly lower. Coated HFM performances have been compared with flat hydrophilic membranes of polyvinylidene fluoride having a similar plasma-polymerized hydrophobic polyfluorosiloxane coating.

scholarly journals Fluoride removal from brackish groundwater by direct contact membrane distillation

2010 ◽  
Vol 61 (12) ◽  
pp. 3178-3187 ◽  
Author(s):  
D. Y. Hou ◽  
J. Wang ◽  
B. Q. Wang ◽  
Z. K. Luan ◽  
X. C. Sun ◽  
...  
Keyword(s):  
Concentration Factor ◽  
Direct Contact ◽  
Polyvinylidene Fluoride ◽  
Membrane Surface ◽  
Membrane Distillation ◽  
Rapid Decline ◽  
Fluoride Removal ◽  
Permeate Flux ◽  
Direct Contact Membrane Distillation ◽  
Module Efficiency

The direct contact membrane distillation (DCMD) applied for fluoride removal from brackish groundwater is presented. The self-prepared polyvinylidene fluoride membrane exhibited high rejection of inorganic salt solutes and a maximum permeate flux 35.6 kgm−2 h−1 was obtained. The feed concentration had no marked impact on the permeate flux and the rejection of fluoride. The precipitation of CaCO3 would clog the hollow fiber inlets and foul the membrane surface with the increase of concentration factor when natural groundwater was used directly as the feed, which resulted in a rapid decline of the module efficiency. This phenomenon was diminished by acidification of the feed. The experimental results showed that the permeate flux and the quality of obtained distillate kept stable before concentration factor reached 5.0 with the acidified groundwater as feed. The membrane module efficiency began to decline gradually when the feed continued to be concentrated, which can be mainly attributed to the formation of CaF2 deposits on the membrane surface. Finally, a 300 h continuous fluoride removal experiment on acidified groundwater was carried out with concentration factor at 4.0, the permeate flux kept stable and the permeate fluoride was not detected.

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