Influence of adding a modified zeolite-Y onto the NiMo/Al2O3 catalyst utilized to produce a diesel fuel with highly reduced sulfur content

Author(s):  
Hamid Karami ◽  
Mohammad Kazemeini ◽  
Saeed Soltanali ◽  
Mehdi Rashidzadeh
2020 ◽  
Vol 38 (5A) ◽  
pp. 779-788
Author(s):  
Marwa N. Kareem ◽  
Adel M. Salih

In this study, the sunflowers oil was utilized as for producing biodiesel via a chemical operation, which is called trans-esterification reaction. Iraqi diesel fuel suffers from high sulfur content, which makes it one of the worst fuels in the world. This study is an attempt to improve the fuel specifications by reducing the sulfur content of the addition of biodiesel fuel to diesel where this fuel is free of sulfur and has a thermal energy that approaches to diesel.20%, 30% and 50% of Biodiesel fuel were added to the conventional diesel. Performance tests and pollutants of a four-stroke single-cylinder diesel engine were performed. The results indicated that the brake thermal efficiency a decreased by (4%, 16%, and 22%) for the B20, B30 and B50, respectively. The increase in specific fuel consumption was (60%, 33%, and 11%) for the B50, B30, and B20 fuels, respectively for the used fuel blends compared to neat diesel fuel. The engine exhaust gas emissions measures manifested a decreased of CO and HC were CO decreased by (13%), (39%) and (52%), and the HC emissions were lower by (6.3%), (32%), and (46%) for B20, B30 and B50 respectively, compared to diesel fuel. The reduction of exhaust gas temperature was (7%), (14%), and (32%) for B20, B30 and B50 respectively. The NOx emission increased with the increase in biodiesel blends ratio. For B50, the raise was (29.5%) in comparison with diesel fuel while for B30 and B20, the raise in the emissions of NOx was (18%) and...


2014 ◽  
Vol 1033-1034 ◽  
pp. 85-89 ◽  
Author(s):  
Guo Xian Yu ◽  
Qian Zhong ◽  
Mei Jin ◽  
Ping Lu

Ultrasound-assisted oxidative desulfurization (UAODS) of diesel fuel in H2O2/Heteropoly acid/Solvent systems, was investigated. Effects of solvent, catalyst, ultrasound and reaction temperature on the oxidation desulfurization of diesel fuel were investigated. When MPA/oil was 2%wt, methanol/diesel fuel was 20%wt, ultrasound power was 400 W and ultrasound time was 10 min, the sulfur content of diesel fuel was decreased from 211 ppm to 19 ppm. The use of ultrasonic irradiation in H2O2/Heteropoly acid/Solvent system significantly improved the efficiency of the oxidation reaction, and solvent was helpful to make the oxidative reaction happen in the same one phase.


2014 ◽  
Vol 910 ◽  
pp. 57-60
Author(s):  
Guo Xian Yu ◽  
Qian Zhong ◽  
Mei Jin ◽  
Jin Huang Wang ◽  
Ping Lu

Deep desulfurization of a hydrotreated diesel fuel was investigated with TBHP oxidation coupled with solvent extraction intensified by ultrasound. The process parameters for the oxidation desulfurization of diesel fuel, such as the type and dosage of catalyst, co-solvent, ultrasound time, molar ratio of TBHP and sulfur were investigated. The results showed that sulfur content of the hydrotreated diesel fuel was reduced from 140 ppm to 12 ppm with using 1%wt of sodium tungstate as catalyst, 20%wt of methanol as co-solvent during the reaction, reaction temperature at 90°C, ultrasound time for 15 min and TBHP/Sulfur molar ratio of 32, and ultrasound irradiation had the obvious reinforcement in oxidative desulfurization of diesel fuel.


RSC Advances ◽  
2020 ◽  
Vol 10 (61) ◽  
pp. 37287-37298
Author(s):  
Suleiman Sabo Bello ◽  
Chao Wang ◽  
Mengjuan Zhang ◽  
Zhennan Han ◽  
Lei Shi ◽  
...  

The CoMo/Al2O3 catalyst was used to upgrade shale oil. Sulfur removal was increased on the spent catalyst. The transition of oxidic Mo-species into active phase MoS2 was observed with recycling. The high sulfidation degree of the CoMo/Al2O3 suppressed deactivation by coking.


2014 ◽  
Vol 953-954 ◽  
pp. 1135-1138 ◽  
Author(s):  
Guo Xian Yu ◽  
Qian Zhong ◽  
Mei Jin ◽  
Jin Huang Wang ◽  
Ping Lu

Deep desulfurization of a hydrotreated diesel fuel was investigated with H2O2oxidation coupled with solvent extraction intensified by ultrasound. The process parameters for the oxidation desulfurization of diesel fuel, such as the type and dosage of catalyst, co-solvent, ultrasound time, molar ratio of H2O2and sulfur were investigated. The results showed that sulfur content of the hydrotreated diesel fuel was reduced from 140 ppm to 10 ppm with using 2%wt of phosphotungstic acid as catalyst, 20%wt of methanol as co-solvent during the reaction, reaction temperature at 90°C, ultrasound time for 10 min and H2O2/S molar ratio of 16, and ultrasound irradiation had the obvious reinforcement in oxidative desulfurization of diesel fuel.


Fuel ◽  
2017 ◽  
Vol 189 ◽  
pp. 340-349 ◽  
Author(s):  
Aline Oliboni de Azambuja ◽  
Francielle Bücker ◽  
Patrícia Dörr de Quadros ◽  
Kateryna Zhalnina ◽  
Raquel Dias ◽  
...  

2009 ◽  
Vol 162 (2-3) ◽  
pp. 1019-1024 ◽  
Author(s):  
Alias Mohd Yusof ◽  
Nik Ahmad Nizam Nik Malek

2011 ◽  
Vol 105 (1-2) ◽  
pp. 1-14 ◽  
Author(s):  
Mun Kyu Kim ◽  
Pyung Soon Kim ◽  
Joon Hyun Baik ◽  
In-Sik Nam ◽  
Byong K. Cho ◽  
...  

2005 ◽  
Vol 55 (7) ◽  
pp. 993-998 ◽  
Author(s):  
Phirun Saiyasitpanich ◽  
Mingming Lu ◽  
Tim C. Keener ◽  
Fuyan Liang ◽  
Soon-Jai Khang

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