scholarly journals Impact of dielectric properties on ionic conductivity of Ce0.9Sm0.1O1.95 via defect interaction

2021 ◽  
pp. 100111
Author(s):  
Sk. Anirban ◽  
Abhigyan Dutta
Author(s):  
Rudramani Tiwari ◽  
Dipendra Kumar Verma ◽  
Devendra Kumar ◽  
Shashikant Yadav ◽  
Krishna Kumar ◽  
...  

Green SPP-PEG hydrogel material, containing Na+ ions, has been synthesized by green chemistry methodology using sodium polyphosphate and polyethylene glycol in water. Hydrogel has amorphous morphology and sandwiched matrix with...


2022 ◽  
Author(s):  
Fernando B Minussi ◽  
Eduardo M. Bertoleti ◽  
Saulo P Reis ◽  
J. Carvalho ◽  
Eudes Borges Araújo

Over the past few years of boosting studies in halide perovskites, the formulation of guanidinium (GA+)-containing compounds has been proven to be an excellent strategy. A system in particular, namely...


2021 ◽  
Vol 12 (5) ◽  
pp. 6114-6123

Solid polymer electrolytes (SPEs) based carboxymethyl cellulose (CMC) with lithium perchlorate (LiClO4) were prepared via solution drop-cast technique. The CMC host is complexed by different concentrations of LiClO4 salt. SPEs were characterized by Electrochemical Impedance Spectroscopy (EIS) and Linear Sweep Voltammetry (LSV) in coin cells with lithium metal electrodes. EIS performed unique results based on various ionic conductivity values and dielectric properties. The higher ionic conductivity (1.32 × 10-5 S/cm) was obtained by SPEs 2 following by short-range ionic transport results based on dielectric properties depending on frequency. SPEs with LiClO4 addition are electrochemically stable over 2 V in lithium battery coin cells from LSV results.


2015 ◽  
Vol 1107 ◽  
pp. 230-235 ◽  
Author(s):  
N.A.M. Noor ◽  
M.I.N. Isa

In this work, solid biopolymer electrolytes (SBE) containing carboxymethyl cellulose (CMC) doped with ammonium thiocyanate (NH4SCN) were prepared via solution casting method. The ionic conductivity and dielectric properties of CMC-NH4SCN system were investigated by electrical impedance spectroscopy in the temperature range of 303-353 K. The dc conductivity shows that the highest ionic conductivity of 6.48 x 10-5 Scm-1 at ambient temperature was obtained when 25 wt.% of NH4SCN was incorporated. The temperature dependence of ionic conductivity revealed that CMC-NH4SCN system was discovered to obey Arrhenius law where the regression value is almost unity (R2≈1). Activation energy of CMC-NH4SCN system was found to decrease with the increment of NH4SCN concentration. The dielectric behaviour of the CMC-NH4SCN system have been analyzed using dielectric permittivity (ε*) and electrical modulus (M*) spectra. Results from dielectric studies showed a non-Debye behaviour of CMC-NH4SCN system.


2019 ◽  
Vol 43 (12) ◽  
pp. 4815-4822 ◽  
Author(s):  
Jin Wang ◽  
Mengde Deng ◽  
Yahui Xiao ◽  
Wentao Hao ◽  
Chengfeng Zhu

A cationic polyelectrolyte with good ionic conductivity and dielectric properties was prepared; the membrane thickness is a key parameter.


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