Changes induced by solvent polarity in electronic absorption spectra of some azo disperse dyes

2010 ◽  
Vol 157 (1) ◽  
pp. 13-17 ◽  
Author(s):  
A. Airinei ◽  
M. Homocianu ◽  
D.O. Dorohoi
Keyword(s):  
Absorption Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Solvent Polarity ◽  
Disperse Dyes ◽  
Azo Disperse Dyes

Discotic liquid crystals of transition metal complexes 34: spectroscopic properties of bis[octakis(3,4-dialkoxy-phenoxy)phthalocyaninato]lutetium(III) complexes

2003 ◽  
Vol 07 (02) ◽  
pp. 105-111 ◽  
Author(s):  
Kazuaki Hatsusaka ◽  
Kazuchika Ohta
Keyword(s):  
Thin Film ◽  
Absorption Spectra ◽  
Electronic Absorption ◽  
Liquid Crystalline ◽  
Electronic Absorption Spectra ◽  
Solvent Polarity ◽  
Spectroscopic Properties ◽  
Temperature Dependent ◽  
First Time ◽  
Hexane Solution

Spectroscopic properties of discotic liquid crystalline bis[octakis(3,4-dialkoxyphenoxy)-phthalocyaninato]lutetium(III) complexes, {[( C n O )2 PhO ]8 Pc }2 Lu (n = 12: 2a and n = 13: 2b), were investigated by recording electronic absorption spectra in the region of 250-2600 nm under three different conditions; solution, mixed solvent solutions, and a thin film at various temperatures. An intermolecular charge transfer (CT) band was found at about 2000-2100 nm both for the n-hexane solution and the thin film. It was established for the first time from the solvent-polarity-dependent and temperature-dependent electronic absorption spectra that the intermolecular CT band is attributable to molecular aggregation.

Changes induced by solvent polarity in electronic absorption spectra of some nucleic acid constituents

2011 ◽  
Vol 312 ◽  
pp. 37-59 ◽  
Author(s):  
Mamdouh S. Masoud ◽  
Ahmed M. Hindawy ◽  
Amina A. Soayed ◽  
Marwa Y. Abd El-Kaway
Keyword(s):  
Nucleic Acid ◽  
Absorption Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Solvent Polarity

scholarly journals Investigation of solvent effects on electronic absorption spectra of some substituted 1,2,4-triazoline-3-thiones

2010 ◽  
Vol 29 (1) ◽  
pp. 43 ◽  
Author(s):  
Mirjana Jankulovska ◽  
Lidija Šoptrajanova ◽  
Ilinka Spirevska ◽  
Katica Čolančevska-Ragenoviќ ◽  
Saško Ristovski
Keyword(s):  
Hydrogen Bonding ◽  
Absorption Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Solvent Polarity ◽  
Linear Solvation Energy Relationships ◽  
Protic Solvents ◽  
Electron Transitions ◽  
Energy Relationships ◽  
Linear Solvation Energy

The influence of the polarity of the solvent and hydrogen bonding on the electronic absorption spectra of some previously synthesized substituted 1,2,4-triazoline-3-thiones was studied. The electronic absorption spectra of investigated compounds were recorded in the region from 190 nm to 360 nm in eight protic (water, ethylene glycol, methanol, ethanol, propan-1-ol, propan-2-ol, butan-1-ol and tert-butanol) and five aprotic (acetonitrile, chloroform, dimethylsulfoxide, dimethylformamide and dioxane) solvents. Their absorption maxima appeared in the region between 250 nm and 260 nm as a result of the electron transitions in the 1,2,4-triazoline-3-thione ring. Using the method of linear solvation energy relationships (LSER), the effects of solvent polarity and hydrogen bonding on the electronic absorption spectra were interpreted. The results have shown that the influence of the aprotic solvents is more significant compared to that of the protic solvents.

scholarly journals Synthesis and dyeing performance of some amphiphilic naphthalimide azo disperse dyes on polyester fabrics

2020 ◽  
Vol 85 (10) ◽  
pp. 1253-1264
Author(s):  
Umar Ameuru ◽  
Mohammed Yakubu ◽  
Kasali Bello ◽  
Peter Nkeonye ◽  
Azim Halimehjani
Keyword(s):  
Absorption Spectra ◽  
Electronic Absorption Spectra ◽  
Polyester Fabric ◽  
Disperse Dyes ◽  
Light Fastness ◽  
Visible Absorption ◽  
Polyester Fabrics ◽  
Dyeing Performance ◽  
Azo Disperse Dyes ◽  
Monoazo Disperse Dyes

A series of monoazo disperse dyes were synthesized by coupling diazotized 4-amino-N-dodecyl-1,8-naphthalimide with N,N-dialkyl anilines and naphthol derivatives. The synthesized intermediates and the dyes were characterized using FTIR, 1H-NMR, 13C-NMR, mass spectroscopy and elemental analysis (CHN). Visible absorption spectra of the dyes were examined in solvents of different polarities. The electronic absorption spectra cover a wavelength (?max) range of 515-535 nm in DMF at uniformly absorption intensity between 1.59-3.00?104 L mol-1 cm-1. The dyes gave deep and bright intense hues of light violet, maroon, pink and neon red on polyester fabrics. The dyes generally showed good washing and perspiration rating but poor to moderate light fastness properties on woven polyester fabric and could be recommended for commercial outlets.

Stereochemistry of [carbonato-bis((S)-prolinato)]cobaltate(III) anion

1984 ◽  
Vol 49 (3) ◽  
pp. 680-683 ◽  
Author(s):  
Bohumil Hájek ◽  
Dagmar Sýkorová ◽  
Jiří Chyba
Keyword(s):  
Absorption Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Cd Spectra

The λ-C1-cis(N), δ-C1-cis(N), λ-C2-cis(N) and δ-C2-cis(N) isomers of the complex K[Co((S)-Pro)2CO3] were chromatographically separated and characterized by their electronic absorption spectra and CD spectra.

Photocolouration of 2,4,4,6-Tetraaryl-4H-pyrans and Their Heteroanalogues: Importance of Hypervalent Photoisomers

1995 ◽  
Vol 60 (10) ◽  
pp. 1621-1633 ◽  
Author(s):  
Stanislav Böhm ◽  
Mojmír Adamec ◽  
Stanislav Nešpůrek ◽  
Josef Kuthan
Keyword(s):  
Reaction Kinetics ◽  
Absorption Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Theoretical Data ◽  
Order Reaction ◽  
Bleaching Process ◽  
First Order ◽  
Photodegradation Products ◽  
Hypervalent Molecules

Molecular geometries of 2,4,4,6-tetraphenyl-4H-pyran (Ia), 4,4-(biphenyl-2,2e-diyl)-2,6-diphenyl-4H-pyran (Ib) and their heterocyclic isomers II-V were optimized by the PM3 method and used for the calculation of electronic absorption spectra by the CNDO/S-CI procedure. Comparison of the theoretical data with experimental UV-VIS absorption spectra made possible to select hypervalent molecules IIIa, IIIb, IVa and IVb being responsible for the photocolouration of 4H-pyrans Ia, Ib, while compounds Va, Vb, VI and VII come into account as possible photodegradation products. The bleaching process of the UV illuminated compound Ia is analyzed in terms of dispersive first-order reaction kinetics.

Niobocene Dichloride and Niobocene Diiodide: Electronic Absorption Spectra and Electron Spin Resonance

1998 ◽  
Vol 63 (5) ◽  
pp. 628-635 ◽  
Author(s):  
Jana Holubová ◽  
Zdeněk Černošek ◽  
Ivan Pavlík
Keyword(s):  
Absorption Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Point Group ◽  
Esr Spectra ◽  
Ligand Field ◽  
Orbital Interaction ◽  
Symmetry Point Group ◽  
Spin Orbital ◽  
Halide Ligands

The effect of the halide ligand on the bonding of niobium in niobocene dichloride and niobocene diiodide was investigated. The electronic absorption spectra of the two compounds in the range of d-d transitions were resolved into four bands corresponding to transitions of the d1 electron between five frontier orbitals in a molecule of symmetry point group C2v. The energies of the frontier molecular orbitals were determined relatively to the energy of the orbitals in the spherically symmetric ligand field formed by the appropriate halide ligands. The effect of the halide ligands on the spin-orbital interaction of the HOMO orbital is discussed qualitatively on the basis the ESR spectra.

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