Effects of critical points of two microemulsion systems on the reaction rate of basic hydrolysis of crystal violet

2017 ◽  
Vol 231 ◽  
pp. 655-662 ◽  
Author(s):  
Lvjie Yang ◽  
Yunhui Xiang ◽  
Lin Chen ◽  
Dan Zhang ◽  
Chenyi Wu ◽  
...  
Langmuir ◽  
2004 ◽  
Vol 20 (3) ◽  
pp. 606-613 ◽  
Author(s):  
L. García-Río ◽  
J. R. Leis ◽  
J. C. Mejuto ◽  
A. Navarro-Vázquez ◽  
J. Pérez-Juste ◽  
...  

2015 ◽  
Vol 12 (1) ◽  
pp. 3910-3918 ◽  
Author(s):  
Dr Remon M Zaki ◽  
Prof Adel M. Kamal El-Dean ◽  
Dr Nermin A Marzouk ◽  
Prof Jehan A Micky ◽  
Mrs Rasha H Ahmed

 Incorporating selenium metal bonded to the pyridine nucleus was achieved by the reaction of selenium metal with 2-chloropyridine carbonitrile 1 in the presence of sodium borohydride as reducing agent. The resulting non isolated selanyl sodium salt was subjected to react with various α-halogenated carbonyl compounds to afford the selenyl pyridine derivatives 3a-f  which compounds 3a-d underwent Thorpe-Ziegler cyclization to give 1-amino-2-substitutedselenolo[2,3-b]pyridine compounds 4a-d, while the other compounds 3e,f failed to be cyclized. Basic hydrolysis of amino selenolo[2,3-b]pyridine carboxylate 4a followed by decarboxylation furnished the corresponding amino selenolopyridine compound 6 which was used as a versatile precursor for synthesis of other heterocyclic compound 7-16. All the newly synthesized compounds were established by elemental and spectral analysis (IR, 1H NMR) in addition to mass spectra for some of them hoping these compounds afforded high biological activity.


1994 ◽  
Vol 29 (12) ◽  
pp. 31-40 ◽  
Author(s):  
Pia Prohaska Brinch ◽  
Kim Rindel ◽  
Kathryn Kalb

Due to the introduction of stricter nutrient effluent standards, many existing wastewater treatment plants performing only primary or secondary treatment are about to be upgraded. As the space available at the plants is, however, often limited, processes are required which will accommodate the need for increased treatment capacity without requiring much more space. In the hydrolysis of primary or pre-precipitated sludge direct-degradable organic carbon is produced which can speed up the reaction rate and increase both biological phosphorus and nitrogen removal. Full-scale tests with dosing of hydrolysate for biological P and N removal, respectively, have shown that this is a most viable process. The use of on-line monitoring has improved the process further.


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