Experimental investigation of thermo-physical properties of geminal dicationic ionic compounds for latent thermal energy storage

2020 ◽  
Vol 307 ◽  
pp. 112994
Author(s):  
Jianlian Liu ◽  
Wenge Yang ◽  
Zhuo Li ◽  
Fei Ren ◽  
Hong Hao
Author(s):  
Paul Gregory Felix ◽  
Velavan Rajagopal ◽  
Kannan Kumaresan

Latent heat thermal energy storage heat exchangers store heat energy by virtue of the phase transition that occurs in the thermal storage media. Since phase change materials (PCMs) are utilized as the media, there is a critical necessity for the appropriate selection of the PCM utilized. Since multiple thermo-physical properties and multiple PCMs are required to be evaluated for the selection, there arises a need for multiple criteria decision making (MCDM) algorithms to be adopted for the selection. But owing to the different weight estimation techniques employed and the voluminous quantity of selection algorithms available, there arises a need for a comparative methodology to be adopted. This study was intended to select an optimal PCM for a sustainable steam cooking application coupled with a thermal energy storage system. In this research study, six PCMs were chosen as the alternatives and five thermo-physical properties were chosen as the criteria for the evaluation. 11 different algorithms were augmented with 3 different weight estimation techniques and therefore a total of 33 algorithms were employed in this study. All of the algorithms have chosen Erythritol as the optimal PCM for the application. The outcomes of the MCDM algorithms have been validated through an intricate Pearson’s correlation coefficient study.


Author(s):  
Hani Tiznobaik ◽  
Donghyun Shin

In a concentrated solar power (CSP), high operating temperature (over 500 °C) is the key for enhancing the efficiency of the system. The operating temperature of the system mainly relies on thermal energy storage (TES) material. Existing TES materials such as mineral oil or paraffin wax cannot be applicable at high temperatures, since these materials are not thermally stable over 400 °C. However, very few materials are suitable and reliable for the high temperatures. Using molten salts (e.g., alkali nitrate, alkali carbonate, alkali chloride, etc.) as thermal energy storage material is an alternative way due to several benefits. They are cheap and environmentally safe compared with the conventional TES materials. They are thermally stable at higher temperatures (over 500 °C). However, their usage is limited due to low thermo-physical properties (e.g. Cp is less than 1.6 J/g°C). The low thermo-physical properties can be improved by dispersing nanoparticles into the salts. In this study, nanomaterials were synthesized by dispersing inorganic nanoparticles into ionic salts. Modulated differential scanning calorimeter (MDSC) was used to measure the heat capacity of the nanomaterials. Scanning electron microscopy (SEM) was used for material characteristic analysis. Hence, the application of the nanomaterials as thermal energy storage in a concentrated solar power was explored.


2020 ◽  
Vol 3 (1) ◽  
pp. p59
Author(s):  
H. I. ElSaeedy ◽  
A. A. S. Al Ahmari ◽  
K. F. Abd El-Rahman ◽  
S. Taha

Here, we investigate the effect of adding nano-silica particles on the thermo-physical properties of the (Na0.6K0.4)NO3 based thermal energy storage systems. Five different systems tagged as M00, M01, M02, M03 and M04, with different nano-silica percentage of 0, 1, 2, 3, and 4 wt%, respectively, were prepared. Various experimental techniques were employed to study the thermo-physical properties of the systems during (solid-solid) phase P1, (solid-liquid) phase P2 and (liquid-solid) phase P3, and to clarify the effect of nano-silica on the thermal energy storage efficiency during both charging and discharging processes. According to the Differential Scanning Calorimeter (DSC) thermal analysis, it was found that the system M02 whose nano-silica addition rate of 2 wt%, has the most favorable thermal characteristics (i.e., highest specific heat and lowest enthalpy change). Moreover, the addition of 2 wt% represents the optimum distribution of nano-silica inside the principal base system M00. This leads to an improvement in the porosity of the system due to the degree of homogeneity caused by the thermophoresis effect distribution, the high surface area of the nano-silica with the activity of the M00 matrix alongside the degree of the alkalinity of nano-silica. Besides, the electric conductivity measurements showed that the 2wt% percentage is the optimum one for thermal energy storage systems.


Author(s):  
Donghyun Shin ◽  
Byeongnam Jo ◽  
Hyun-eun Kwak ◽  
Debjyoti Banerjee

The aim of this study is to investigate the enhancement of thermal properties of various high temperature nanofluids for solar thermal energy storage application. In concentrating solar power (CSP) systems, the thermo-physical properties of the heat transfer fluids (HTF) and the thermal energy storage (TES) materials are key to enhancing the overall system efficiency. Molten salts, such as alkali nitrates, alkali carbonates, or eutectics are considered as alternatives to conventional HTF to extend the capabilities of CSP. However, there is limited usage of molten salt eutectics as the HTF material, since the heat capacity of the molten salts are lower than that of conventional HTF. Nanofluid is a mixture of a solvent and nanoparticles. Well dispersed nanoparticles can be used to enhance thermo-physical properties of HTF. In this study, silica (SiO2) and alumina (Al2O3) nanoparticles as well as carbon nanotubes (CNT) were dispersed into a molten salt and a commercially available HTF. The specific heat capacity of the nanofluids were measured and applicability of such nanofluid materials for solar thermal storage applications were explored. Measurements performed using the carbonate eutectics and commercial HTF that are doped with inorganic and organic nano-particles show specific heat capacity enhancements exceeding 5–20% at concentrations of 0.05% to 2.0% by weight. Dimensional analyses and computer simulations were performed to predict the enhancement of thermal properties of the nanofluids. The computational studies were performed using Molecular Dynamics (MD) simulations.


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