Lanthanide complexes with oda, ida, and nta: From discrete coordination compounds to supramolecular assemblies

Antiproliferative evaluation and supramolecular assemblies of Co(ii) and Zn(ii) coordination compounds involving cooperative anion–π and unconventional DNA-relevant π-stacked hydrogen bonded arrays.

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Discrete Supramolecular Assemblies of Porphyrins Mediated by Coordination Compounds

ChemInform ◽

10.1002/chin.200336256 ◽

2003 ◽

Vol 34 (36) ◽

Author(s):

Elisabetta Iengo ◽

Ennio Zangrando ◽

Enzo Alessio

Keyword(s):

Coordination Compounds ◽

Supramolecular Assemblies

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Lanthanide Complexes with Carbacylamidophosphates: The First Registration of Chelate Coordination of the Neutral Ligand Form in the Structure of Di-(N,Nf-tetramethyl-NM -benzoylphosphoryl- triamide)cerium(III) Nitrate

Zeitschrift für Naturforschung B ◽

10.1515/znb-2000-0704 ◽

2000 ◽

Vol 55 (7) ◽

pp. 576-582 ◽

Cited By ~ 16

Author(s):

Katerina E. Gubina ◽

Vladimir A. Ovchynnikov ◽

Vladimir M. Amirkhanov ◽

Helmut Fischer ◽

Rüdiger Stumpf ◽

...

Keyword(s):

Molecular Structure ◽

Crystal Structure ◽

Nmr Spectroscopy ◽

Coordination Compounds ◽

Metal Ion ◽

Lanthanide Complexes ◽

Carbonyl Oxygen ◽

Neutral Ligand ◽

Crystal Data ◽

X Ray

Abstract The coordination compounds of the general formula Ln(HL)2(NO3)3, (where Ln = La - Eu (without Pm), HL = C6H5C(O)NHP(O)[N(CH3)2]2, N,Nʹ-tetramethyl-Nʺ-benzovlphosphoryl-triamide) have been synthesized and characterized by means of IR, UV-VIS, 1H, 31P NMR spectroscopy, and X-ray analysis. The complexes are isostructural according to X-ray powder diffraction studies. The crystal structure of the cerium(lll) complex has been determined. Crystal data: monoclinic, P21/c, with a = 10.503(9), b = 15.62(2), c = 21.91(2) Å, β = 99.56(8)°, Z = 4, V = 3546(6) Å3, R1= 0.0550, wR2 = 0.1383 for 6970 unique reflections used. The complex has a molecular structure. Neutral phosphoryltriamide ligands are coordinated to the metal ion in a bidentate manner via phosphoryl and carbonyl oxygen atoms with formation of six membered chelate rings. The coordination polyhedron of the Ce atom is a sphenocorona; C.N. = 10 (4 O[HL] + 6 O [NO3-]).

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Spectroscopic studies of lanthanide complexes of varying nuclearity based on a compartmentalised ligand

Dalton Transactions ◽

10.1039/c5dt02563j ◽

2015 ◽

Vol 44 (39) ◽

pp. 17175-17188 ◽

Cited By ~ 11

Author(s):

Daniela Olea-Román ◽

Nicolas Bélanger-Desmarais ◽

Marcos Flores-Álamo ◽

Claudia Bazán ◽

Félix Thouin ◽

...

Keyword(s):

Coordination Compounds ◽

Lanthanide Complexes ◽

Spectroscopic Studies ◽

Nir Luminescence

Spectroscopic studies of lanthanide-based coordination compounds of varying nuclearity with a compartmental ligand which show NIR luminescence.

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The role of intermolecular interactions involving halogens in the supramolecular architecture of a series of Mn(ii) coordination compounds

RSC Advances ◽

10.1039/c5ra25192c ◽

2016 ◽

Vol 6 (3) ◽

pp. 2422-2430 ◽

Cited By ~ 15

Author(s):

Hamid Reza Khavasi ◽

Alireza Ghanbarpour ◽

Alireza Azhdari Tehrani

Keyword(s):

Intermolecular Interactions ◽

Coordination Compounds ◽

Structural Changes ◽

Supramolecular Assemblies ◽

Supramolecular Architecture

This study reveals the role of halogen-involving interactions in structural changes of supramolecular assemblies of manganese(ii) complexes including N-(4-halo)phenyl picolinamide ligands.

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Novel Lanthanide (III) Complexes Derived from an Imidazole–Biphenyl–Carboxylate Ligand: Synthesis, Structure and Luminescence Properties

Molecules ◽

10.3390/molecules26226942 ◽

2021 ◽

Vol 26 (22) ◽

pp. 6942

Author(s):

Monica-Cornelia Sardaru ◽

Narcisa Laura Marangoci ◽

Sergiu Shova ◽

Dana Bejan

Keyword(s):

Coordination Compounds ◽

Lanthanide Complexes ◽

Bidentate Ligand ◽

Carboxylate Ligand ◽

Monoclinic Space Group ◽

X Ray Diffraction ◽

X Ray ◽

Characteristic Emission ◽

Solvothermal Conditions ◽

State Luminescence

A series of neutral mononuclear lanthanide complexes [Ln(HL)2(NO3)3] (Ln = La, Ce, Nd, Eu, Gd, Dy, Ho) with rigid bidentate ligand, HL (4′-(1H-imidazol-1-yl)biphenyl-4-carboxylic acid) were synthesized under solvothermal conditions. The coordination compounds have been characterized by infrared spectroscopy, thermogravimetry, powder X-ray diffraction and elemental analysis. According to X-ray diffraction, all the complexes are a series of isostructural compounds crystallized in the P2/n monoclinic space group. Additionally, solid-state luminescence measurements of all complexes show that [Eu(HL)2(NO3)3] complex displays the characteristic emission peaks of Eu(III) ion at 593, 597, 615, and 651 nm.

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Designed Polynuclear Lanthanide Complexes for Quantum Information Processing

Dalton Transactions ◽

10.1039/d1dt01862k ◽

2021 ◽

Author(s):

David Aguilà ◽

Olivier Roubeau ◽

Guillem Aromí

Keyword(s):

Information Processing ◽

Quantum Information ◽

Coordination Compounds ◽

Lanthanide Complexes ◽

Quantum Information Processing ◽

Organic Ligands

The design of dissymmetric organic ligands featuring combinations of 1,3-diketone and 2,6-diacetylpyridine coordination pockets has been exploited to produce dinuclear and trinuclear lanthanide-based coordination compounds. These molecules exhibit two or...

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