A porous Cd(II) metal-organic framework with high adsorption selectivity for CO2 over CH4

2017 ◽  
Vol 1136 ◽  
pp. 140-143 ◽  
Author(s):  
Chunlan Zhu
Keyword(s):  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Selectivity ◽  
Metal Organic ◽  
Organic Framework

A new anionic metal–organic framework showing tunable emission by lanthanide(III) doping and highly selective CO2 adsorption properties

RSC Advances ◽  
2015 ◽  
Vol 5 (31) ◽  
pp. 24655-24660 ◽  
Author(s):  
Rong-Ying Chen ◽  
Dan Tian ◽  
Yun-Wu Li ◽  
Ying-Bin Lv ◽  
Hong-Wei Sun ◽  
...  
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
High Adsorption ◽  
Adsorption Selectivity ◽  
Metal Organic ◽  
Tunable Emission ◽  
Organic Framework

A 3D porous anionic MOF (1), decorated with -NH2 and N sites, can serve as a host for the encapsulation of lanthanide(iii) cations for emission tuning. Besides, it also shows high adsorption selectivity for CO2 over CH4 and N2 at 273 K.

A microporous yttrium metal–organic framework of an unusual nia topology for high adsorption selectivity of C2H2and CO2over CH4at room temperature

2017 ◽  
Vol 1 (10) ◽  
pp. 1982-1988 ◽  
Author(s):  
Kang Liu ◽  
Xu Li ◽  
Dingxuan Ma ◽  
Yi Han ◽  
Baiyan Li ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Selectivity ◽  
Basic Sites ◽  
Metal Organic ◽  
Organic Framework

A new microporous yttrium MOF Y-H3TDPAT with Lewis basic sites on the pore surfaces was hydrothermally synthesized and structurally characterized as an unusualniatopology.

High Adsorption Capacities and Two-Step Adsorption of Polar Adsorbates on Copper–Benzene-1,3,5-tricarboxylate Metal–Organic Framework

2013 ◽  
Vol 117 (35) ◽  
pp. 18100-18111 ◽  
Author(s):  
Tom R. C. Van Assche ◽  
Tim Duerinck ◽  
Juan José Gutiérrez Sevillano ◽  
Sofia Calero ◽  
Gino V. Baron ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Capacities ◽  
Metal Organic ◽  
Organic Framework

Synthesis, Structure, and Properties of a Chiral Zinc(II) Metal-Organic Framework Featuring Linear Trinuclear Secondary Building Blocks

2012 ◽  
Vol 65 (12) ◽  
pp. 1662 ◽  
Author(s):  
Zilu Chen ◽  
Chuanbing Zhang ◽  
Xianlin Liu ◽  
Zhong Zhang ◽  
Fupei Liang
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Building Blocks ◽  
Triangular Prism ◽  
Structure And Properties ◽  
Adsorption Selectivity ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

A chiral metal-organic framework formulated as [Zn3(L-TMTA)2(4,4′-bpy)4]·24H2O (1) was prepared from the reaction of Zn(NO3)2·6H2O with trimesoyltri(L-alanine) (L-TMTAH3) in the presence of 4,4′-bipyridine (4,4′-bpy). Compound 1 features linear trinuclear secondary building blocks [Zn3(syn-syn-COO)2(μ2,η3-COO)2]2+. Each linear trinuclear secondary building block is further linked to another eight ones around it by four L-TMTA3– ligands and eight 4,4′-bpy ligands, leading to the construction of a uninodal three-dimensional framework with triangular prism-like one-dimensional channels. Dehydrated compound 1 displays remarkable adsorption selectivity on CO2 and water vapour over N2 gas.

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