High Adsorption Capacities and Two-Step Adsorption of Polar Adsorbates on Copper–Benzene-1,3,5-tricarboxylate Metal–Organic Framework

2013 ◽  
Vol 117 (35) ◽  
pp. 18100-18111 ◽  
Author(s):  
Tom R. C. Van Assche ◽  
Tim Duerinck ◽  
Juan José Gutiérrez Sevillano ◽  
Sofia Calero ◽  
Gino V. Baron ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Capacities ◽  
Metal Organic ◽  
Organic Framework

PPI-Dendrimer-Functionalized Magnetic Metal–Organic Framework (Fe3O4@MOF@PPI) with High Adsorption Capacity for Sustainable Wastewater Treatment

2020 ◽  
Vol 12 (22) ◽  
pp. 25294-25303 ◽  
Author(s):  
Hossein Shahriyari Far ◽  
Mahdi Hasanzadeh ◽  
Mohammad Shabani Nashtaei ◽  
Mahboubeh Rabbani ◽  
Aminoddin Haji ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Adsorption Capacity ◽  
Metal Organic Framework ◽  
High Adsorption ◽  
Magnetic Metal ◽  
Metal Organic ◽  
High Adsorption Capacity ◽  
Sustainable Wastewater Treatment ◽  
Organic Framework

Heterometallic trinuclear cluster-based microporous metal-organic framework with high adsorption selectivity of CO2 over N2

2020 ◽  
Vol 121 ◽  
pp. 108202
Author(s):  
Ying Song ◽  
Bing Wang ◽  
Yi Liu ◽  
Li-Jian Guo ◽  
Jin-Jin Cao ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Selectivity ◽  
Trinuclear Cluster ◽  
Metal Organic ◽  
Organic Framework

A new anionic metal–organic framework showing tunable emission by lanthanide(III) doping and highly selective CO2 adsorption properties

RSC Advances ◽  
2015 ◽  
Vol 5 (31) ◽  
pp. 24655-24660 ◽  
Author(s):  
Rong-Ying Chen ◽  
Dan Tian ◽  
Yun-Wu Li ◽  
Ying-Bin Lv ◽  
Hong-Wei Sun ◽  
...  
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
High Adsorption ◽  
Adsorption Selectivity ◽  
Metal Organic ◽  
Tunable Emission ◽  
Organic Framework

A 3D porous anionic MOF (1), decorated with -NH2 and N sites, can serve as a host for the encapsulation of lanthanide(iii) cations for emission tuning. Besides, it also shows high adsorption selectivity for CO2 over CH4 and N2 at 273 K.

scholarly journals Preparation and exceptional adsorption performance of porous MgO derived from a metal–organic framework

RSC Advances ◽  
2017 ◽  
Vol 7 (26) ◽  
pp. 16189-16195 ◽  
Author(s):  
Xian-He Shi ◽  
Jin-Jin Ban ◽  
Li Zhang ◽  
Zhi-Peng Sun ◽  
Dian-Zeng Jia ◽  
...  
Keyword(s):  
Congo Red ◽  
Metal Organic Framework ◽  
Adsorption Performance ◽  
Adsorption Capacities ◽  
Metal Organic ◽  
Organic Framework

Porous MgO-hex and MgO-dhp materials were synthesized by annealing metal–organic framework [NH4][Mg(HCOO)3], and exhibit excellent adsorption capacities toward Congo red.

High storage capacity and separation selectivity for C2 hydrocarbons over methane in the metal–organic framework Cu–TDPAT

2014 ◽  
Vol 2 (38) ◽  
pp. 15823-15828 ◽  
Author(s):  
Kang Liu ◽  
Dingxuan Ma ◽  
Baiyan Li ◽  
Yi Li ◽  
Kexin Yao ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Enthalpy ◽  
High Storage Capacity ◽  
Metal Organic ◽  
High Adsorption Capacity ◽  
C2 Hydrocarbons ◽  
High Storage ◽  
Organic Framework

We report an rht-type metal–organic framework (MOF) which exhibits a high adsorption capacity for C2 hydrocarbons and excellent selectivity over CH4. This MOF displays the highest reported C2H2–CH4 selectivity of 127.1 as well as a record high value for C2H4 adsorption enthalpy (49.5 kJ mol−1).

A microporous yttrium metal–organic framework of an unusual nia topology for high adsorption selectivity of C2H2and CO2over CH4at room temperature

2017 ◽  
Vol 1 (10) ◽  
pp. 1982-1988 ◽  
Author(s):  
Kang Liu ◽  
Xu Li ◽  
Dingxuan Ma ◽  
Yi Han ◽  
Baiyan Li ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Selectivity ◽  
Basic Sites ◽  
Metal Organic ◽  
Organic Framework

A new microporous yttrium MOF Y-H3TDPAT with Lewis basic sites on the pore surfaces was hydrothermally synthesized and structurally characterized as an unusualniatopology.

Metal organic framework-graphene nano-composites for high adsorption removal of DBT as hazard material in liquid fuel

2019 ◽  
Vol 373 ◽  
pp. 447-458 ◽  
Author(s):  
Aya M. Matloob ◽  
Dalia R. Abd El-Hafiz ◽  
L. Saad ◽  
S. Mikhail ◽  
D. Guirguis
Keyword(s):  
Liquid Fuel ◽  
Metal Organic Framework ◽  
Nano Composites ◽  
High Adsorption ◽  
Adsorption Removal ◽  
Metal Organic ◽  
Organic Framework

Integrating multiple adsorption sites and tortuous diffusion paths into a metal–organic framework for C3H4/C3H6 separation

2019 ◽  
Vol 7 (44) ◽  
pp. 25254-25257 ◽  
Author(s):  
Xue-Qian Wu ◽  
Yabo Xie ◽  
Jing-Hao Liu ◽  
Tao He ◽  
Yong-Zheng Zhang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Sites ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Diffusion Paths ◽  
High Adsorption Capacity ◽  
Multiple Adsorption ◽  
Excellent Selectivity ◽  
Organic Framework

By integrating open metal sites, Lewis basic sites, and tortuous diffusion paths, a new metal–organic framework has been designed and synthesized, which exhibits high adsorption capacity and excellent selectivity for separating a C3H4/C3H6 mixture.

scholarly journals High CO2 Adsorption Enthalpy Enabled by Uncoordinated N-Heteroatom Sites of a 3D Metal-Organic Framework

2019 ◽  
Vol 2019 ◽  
pp. 1-5 ◽  
Author(s):  
Yongting Zhao ◽  
Yiming Xie
Keyword(s):  
Room Temperature ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
X Ray Diffraction ◽  
High Adsorption ◽  
Adsorption Enthalpy ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

A 3D metal-organic framework (MOF), Mn2L2(H2O)2 · (DMF) {H2L = 5- (Pyridin-2-yl)-3, 3′-bi (1H-1,2,4-triazole)} (1) with uncoordinated N-heteroatom sites, has been obtained through hydrothermal method and structurally characterized by X-ray structural analysis, powder X-ray diffraction (PXRD), and thermal analysis (TGA). The framework of compound 1 exhibits fascinating adsorption properties and shows high adsorption enthalpy of CO2. The experimental results prove which uncoordinated nitrogen heteroatom sites can markedly increase the reciprocity between host frame and CO2 at room temperature.

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