A facile route for the synthesis of new 1D copper(II) coordination polymer as precursors for preparation of nano structures: Crystallography and Hirshfeld surface analysis

2020 ◽  
Vol 1200 ◽  
pp. 127020 ◽  
Author(s):  
Nozar Fayaz bakhsh ◽  
Mohammad Jaafar Soltanian Fard ◽  
Payam Hayati ◽  
Ardavan Masoudiasl ◽  
Jan Janczak
Keyword(s):  
Coordination Polymer ◽  
Surface Analysis ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis ◽  
Nano Structures ◽  
Facile Route

A Three‐Dimensional Pentanuclear Co(II) Coordination Polymer: Structural Topology, Hirshfeld Surface Analysis and Magnetic Properties

2020 ◽  
Vol 5 (43) ◽  
pp. 13732-13737
Author(s):  
Saima Kamaal ◽  
Mayak Gupta ◽  
Rupali Mishra ◽  
Arif Ali ◽  
Abdullah Alarifi ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymer ◽  
Surface Analysis ◽  
Three Dimensional ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis ◽  
Structural Topology

A new ladder-type silver(I) coordination polymer with 4,4′-bipyridine and 4-[(4-carboxybenzyloxy)methyl]benzoate ligands: synthesis, crystal structure, fluorescence properties and Hirshfeld surface analysis

2020 ◽  
Vol 76 (10) ◽  
pp. 952-957
Author(s):  
Zhao Chen ◽  
Zilong Zhang ◽  
Chong Zhang ◽  
Yu Xiao
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Surface Analysis ◽  
Silver Ions ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis ◽  
Fluorescence Properties ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hydrothermal Methods

A novel ladder-type coordination polymer (CP), poly[(μ-4,4′-bipyridine-κ2 N:N′){μ-4-[(4-carboxybenzyloxy)methyl]benzoato-κO}silver(I)](Ag—Ag), [Ag(C16H13O5)(C10H8N2)] n or [Ag(HL)(4,4′-bpy)] n {H2 L is 4,4′-[oxybis(methylene)]dibenzoic acid and 4,4′-bpy is 4,4′-bipyridine}, was synthesized using hydrothermal methods. The complex was characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction, and is a ladder-type CP which exhibits an obvious Ag—Ag interaction. The legs of the ladder are formed by parallel 4,4′-bipy ligands and silver ions, and the rungs are constructed by Ag—Ag interactions. A Hirshfeld surface analysis was carried out and is discussed in detail. The complex also displays favourable fluorescence properties.

Sign in / Sign up

Export Citation Format

Share Document