Peripheral octa-substituted metal-free, cobalt(II) and zinc(II) phthalocyanines bearing coumarin and chloro groups: Synthesis, characterization, spectral and electrochemical properties

Polyhedron ◽  
2012 ◽  
Vol 48 (1) ◽  
pp. 31-42 ◽  
Author(s):  
Selçuk Altun ◽  
Ali Rıza Özkaya ◽  
Mustafa Bulut
1993 ◽  
Vol 71 (5) ◽  
pp. 742-753 ◽  
Author(s):  
Yu-Hong Tse ◽  
Alok Goel ◽  
Mougang Hu ◽  
A. B. P. Lever ◽  
C. C. Leznoff ◽  
...  

The spectral and electrochemical properties of tetrabenzo[5,10,15]triazaporphine (TBTAP) and its magnesium derivatives having a long alkyl chain attached to the meso carbon have been studied. Both metal-free and metallated species show typical metal-free phthalocyanine-like spectra. Two reduction and two oxidation redox couples have been observed. The cation, anion, and dianion species of these porphyrin derivatives have been electrochemically generated and their electronic spectra are recorded.


2013 ◽  
Vol 407 ◽  
pp. 82-90 ◽  
Author(s):  
Gianfranco Cattenacci ◽  
Massimiliano Aschi ◽  
Giuseppe Graziano ◽  
Andrea Amadei

2015 ◽  
Vol 44 (25) ◽  
pp. 11491-11503 ◽  
Author(s):  
Ana R. Freitas ◽  
Mónica Silva ◽  
M. Luísa Ramos ◽  
Licínia L. G. Justino ◽  
Sofia M. Fonseca ◽  
...  

Having the HOMO of chromium(iii) tris-(8-hydroxyquinolinate) mainly on metal 3d orbitals and the LUMO on the ligand leads to increased electrochemical stability.


1998 ◽  
Vol 37 (18) ◽  
pp. 4567-4572 ◽  
Author(s):  
Francis D'Souza ◽  
Melvin E. Zandler ◽  
Pietro Tagliatesta ◽  
Zhongping Ou ◽  
Jianguo Shao ◽  
...  

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