Evolution from discrete mononuclear complexes to trinuclear linear cluster and 2D coordination polymers of Mn(II) with dihydrazone Schiff bases: preparation, structure and thermal behavior

Polyhedron ◽  
2021 ◽  
pp. 115329
Author(s):  
Lilia Croitor ◽  
Maria Cocu ◽  
Ion Bulhac ◽  
Paulina N. Bourosh ◽  
Victor Ch. Kravtsov ◽  
...  
Keyword(s):  
Thermal Behavior ◽  
Schiff Bases ◽  
Coordination Polymers ◽  
Mononuclear Complexes ◽  
Linear Cluster

Syntheses, Spectroscopy And Crystal Structures Of (R)-N-(1-Aryl-Ethyl)Salicylaldimines And [Rh{(R)-N-(1-Aryl-Ethyl)Salicylaldiminato}(η4-Cod)] Complexes

2007 ◽  
Vol 62 (6) ◽  
pp. 807-817 ◽  
Author(s):  
Mohammed Enamullah ◽  
A.K.M. Royhan Uddin ◽  
Anne-Christine Chamayou ◽  
Christoph Janiak
Keyword(s):  
Mass Spectrometry ◽  
Schiff Base ◽  
Schiff Bases ◽  
Structure Determination ◽  
Chelate Ring ◽  
Optical Rotation ◽  
X Ray ◽  
Mononuclear Complexes ◽  
Chiral Schiff Base ◽  
C Nmr

Condensation of salicylaldehyde with enantiopure (R)-(1-aryl-ethyl)amines yields the enantiopure Schiff bases (R)-N-(1-aryl-ethyl)salicylaldimine (HSB*; aryl = phenyl, 2-methoxyphenyl, 3- methoxyphenyl, 4-methoxyphenyl (4), 4-bromophenyl (5), 2-naphthyl). These Schiff bases readily react with dinuclear (acetato)(η4-cycloocta-1,5-diene)rhodium(I), [Rh(μ-O2CMe)(η4-cod)]2, to afford the mononuclear complexes, cyclooctadiene-((R)-N-(1-aryl-ethyl)salicylaldiminato-κ2N,O)- rhodium(I), [Rh(SB∗)(η4-cod)] (SB* = deprotonated chiral Schiff base = salicylaldiminate; aryl = phenyl (7), 2-methoxyphenyl, 4-methoxyphenyl, 4-bromophenyl, 2-naphthyl). The complexes have been characterized by IR, UV/vis, 1H/13C NMR and mass spectrometry, optical rotation as well as by single-crystal X-ray structure determination for 4, 5 and 7. The structure of 5 shows C-Br· · ·π contacts. Compound 7 is only the second example of a Rh(η4-cod) complex with a six-membered Rh-N,O-chelate ring

Ferroelectric Liquid Crystals: Synthesis and Thermal Behavior of Optically Active, Three-Ring Schiff Bases and Salicylaldimines

2018 ◽  
Vol 13 (8) ◽  
pp. 1012-1023 ◽  
Author(s):  
Bhyranalyar N. Veerabhadraswamy ◽  
Doddamane S. Shankar Rao ◽  
Channabasaveshwar V. Yelamaggad
Keyword(s):  
Liquid Crystals ◽  
Thermal Behavior ◽  
Schiff Bases ◽  
Optically Active ◽  
Ferroelectric Liquid Crystals

Copper(II) complexes with Schiff bases: Structures and thermal behavior

2014 ◽  
Vol 55 (6) ◽  
pp. 1067-1074 ◽  
Author(s):  
S. I. Dorovskikh ◽  
N. V. Kuratieva ◽  
S. V. Tkachev ◽  
S. V. Trubin ◽  
P. A. Stabnikov ◽  
...  
Keyword(s):  
Thermal Behavior ◽  
Schiff Bases

Two new metal-organic coordination polymers of lead with O-, N-donor ligands: Synthesis, characterization, luminescence and thermal behavior

2013 ◽  
Vol 197 ◽  
pp. 46-52 ◽  
Author(s):  
Abhinandan Rana ◽  
Swapan Kumar Jana ◽  
Madhusudan Bera ◽  
Debdoot Hazari ◽  
Durga Sankar Chowdhuri ◽  
...  
Keyword(s):  
Thermal Behavior ◽  
Coordination Polymers ◽  
Donor Ligands ◽  
Metal Organic

Dinuclear organotin(IV) coordination polymers derived from Schiff bases with l -aspartic acid

2017 ◽  
Vol 838 ◽  
pp. 24-36 ◽  
Author(s):  
Tushar S. Basu Baul ◽  
Pelesakuo Kehie ◽  
Andrew Duthie ◽  
Herbert Höpfl
Keyword(s):  
Aspartic Acid ◽  
Schiff Bases ◽  
Coordination Polymers

scholarly journals Effect of Substitutions on Thermal Behavior of Symmetric Doubleschiff Bases of 1,1’-Bis(4-Amino Phenyl)Cyclohexane

2016 ◽  
Vol 63 ◽  
pp. 145-149
Author(s):  
Bhavesh J. Gangani ◽  
Parsotam H. Parsania
Keyword(s):  
Thermal Properties ◽  
Thermal Behavior ◽  
Kinetic Parameters ◽  
Schiff Bases ◽  
Frequency Factor ◽  
Entropy Change ◽  
Nitrogen Atmosphere ◽  
Energy Of Activation ◽  
Thermo Gravimetric ◽  
Degradation Kinetic

Thermo gravimetric analyses of some symmetric double Schiff bases of 1, 1’- bis (4-amino phenyl) cyclohexane (SDSB-1 to SDSB-6) was carried out at 100C/min in nitrogen atmosphere. Schiff bases are thermally stable up to 200-285°C and followed two step degradation kinetic. Various kinetic parameters such as order of degradation (n), energy of activation (Ea), frequency factor (A) and entropy change (ΔS) were derived accordingly Anderson-Freeman method interpreted in light of nature of the substituents. The nature, size and position of substituents affected thermal properties of the Schiff bases.

Synthesis, Characterization and Thermal Behavior of Two 4d-4f Coordination Polymers Based on N and O Donor Ligands

2009 ◽  
Vol 635 (2) ◽  
pp. 393-398 ◽  
Author(s):  
Qing-Yang Lian ◽  
Chun-De Huang ◽  
Rong-Hua Zeng ◽  
Yong-Cai Qiu ◽  
Ji-Xia Mou ◽  
...  
Keyword(s):  
Thermal Behavior ◽  
Coordination Polymers ◽  
Donor Ligands

Thermo-sensitive luminescence of lanthanide complexes, clusters, coordination polymers and metal–organic frameworks with organic photosensitizers

2019 ◽  
Vol 7 (25) ◽  
pp. 7494-7511 ◽  
Author(s):  
Yasuchika Hasegawa ◽  
Yuichi Kitagawa
Keyword(s):  
Coordination Polymers ◽  
Lanthanide Complexes ◽  
Metal Organic Frameworks ◽  
Temperature Dependent ◽  
Mononuclear Complexes ◽  
Recent Advances ◽  
Metal Organic ◽  
Polynuclear Clusters

Historical and recent advances of lanthanide mononuclear complexes, polynuclear clusters, coordination polymers (CPs) and metal–organic frameworks (MOFs) with temperature-dependent luminescence are reviewed for future thermo-sensitive paints.

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