Synthesis and performance of flame retardant additives based on cyclodiphosph(V)azane of sulfaguanidine,1,3-di-[N/-2-pyrimidinylsulfanilamide]-2, 2, 2.4, 4, 4-hexachlorocyclodiphosph(V)azane and 1,3-di-[N/-2-pyrimidinylsulfanilamide]-2, 4-di[aminoacetic acid]-2, 4-dichlorocyclodiphosph(V)azane incorporated into polyurethane varnish

2012 ◽  
Vol 74 (3) ◽  
pp. 615-621 ◽  
Author(s):  
H. Abd El-Wahab ◽  
M. Abd El-Fattah ◽  
N. Abd El-Khalik ◽  
Carmen M. Sharaby
Keyword(s):  
Flame Retardant ◽  
Aminoacetic Acid ◽  
And Performance

scholarly journals Ammonium Polyphosphate Intercalated Layered Double Hydroxide and Zinc Borate as Highly Efficient Flame Retardant Nanofillers for Polypropylene

Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1114 ◽  
Author(s):  
Yanshan Gao ◽  
Qiang Wang ◽  
Weiran Lin
Keyword(s):  
Flame Retardant ◽  
Ammonium Polyphosphate ◽  
Zinc Borate ◽  
Polypropylene Composites ◽  
Flame Retardant Property ◽  
Thermogravimetric Analyzer ◽  
Mixing Method ◽  
And Performance ◽  
Double Hydroxide ◽  
Double Hydroxides

We found in our previous study that layered double hydroxides (LDHs) which undergo aqueous miscible organic solvent treatment (AMOST) can tune the hydrophobicity surface of LDHs to be hydrophobic, and then the solvent mixing method can be used to prepare polymer/LDH nanocomposites. However, flame retardant property is not very high if LDHs are only used. In this present work, ammonium polyphosphate (APP) intercalated LDHs and zinc borate (ZB) was incorporated into a polypropylene (PP) matrix using the solvent mixing method. The structures, morphologies, and performance of the composites were characterized carefully. The peak heat release rate (PHRR) reduction of PP containing 10 and 20 wt % APP-LDH reached 27% and 55%, respectively, which increased up to 63% compared with PP/CO3-LDH. After incorporating 2 wt % ZB in the PP/APP-LDH system, the flame retardant property was further improved. Polypropylene composites with 20 wt % APP-LDH and 2 wt % ZB showed a 58% PHRR reduction. In addition, thermogravimetric analyzer (TGA) results indicated that the addition of APP-LDH and ZB improved the temperature at 50% weight loss (T50%) and the char formation of the materials significantly.

scholarly journals Mechanical and Flame-Retardant Properties of Exoxy Epikote 240/Epoxidized Linseed Oil Composites Using Fiber-Glass

2020 ◽  
Vol 39 (1) ◽  
pp. 9-20 ◽  
Author(s):  
Nguyen Tuan Anh
Keyword(s):  
Mechanical Strength ◽  
Flame Retardant ◽  
Polymer Composite ◽  
Flame Retardants ◽  
Linseed Oil ◽  
Woven Fabric ◽  
Antimony Trioxide ◽  
Flame Retardant Properties ◽  
And Performance ◽  
Epoxidized Linseed Oil

Flammability of polymer composite appears to be one of the greatest threats and hence limits its advanced applications. Polymer composite materials can be designed to obtain wide ranges of properties in comparison with traditional materials. However, almost common polymers include the intrinsic flammability, restricting their applications in spite of their flexibility and performance efficiency. In this study, a material based on epoxy Epikote 240 resin 90 phr and epoxidized linseed oil 10 phr was prepared. In order to improve the material's flame retardancy ability but maintain its mechanical strength, the mixture of flame retardants including 9 phr antimony trioxide and 11 phr chlorinated paraffins along with amin compounds as a curing agent were added into the material. In addition, E-glass woven fabric (E 600g/m2 ) was used to improve mechanical strength of the material. As a result, the material was considered as the flame- retardant material with LOI index to be 30.3%.

Synthesis and performance of intrinsically flame-retardant, low-smoke biobased vinyl ester resin

2022 ◽  
pp. 105158
Author(s):  
Xin Zhang ◽  
Weiwei Zhang ◽  
Ye-Tang Pan ◽  
Lijun Qian ◽  
Zhaolu Qin ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Vinyl Ester ◽  
Vinyl Ester Resin ◽  
And Performance

Synthesis and performance of star-shaped aluminum phosphinate flame retardant

2016 ◽  
Vol 124 (3) ◽  
pp. 1399-1409 ◽  
Author(s):  
Liyong Zou ◽  
Jiyan Liu ◽  
Xueqing Liu ◽  
Xiaomeng Wang ◽  
Jia Chen
Keyword(s):  
Flame Retardant ◽  
And Performance

Preparation and Performance of a P–N Containing Intumescent Flame Retardant Based on Hydrolyzed Starch

2017 ◽  
Vol 56 (16) ◽  
pp. 1760-1771 ◽  
Author(s):  
Hao Qu ◽  
Ruilan Fan ◽  
Jianli Yuan ◽  
Bingbing Liu ◽  
Lijie Sun ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Intumescent Flame Retardant ◽  
And Performance

scholarly journals Environmental and Performance Assessment of Fabricated Hydrophobic and Flame-Retardant Cotton Fabrics with Functional Integrated Graphene

2021 ◽  
Author(s):  
Jia Xu ◽  
Yifan Zhi ◽  
Sainan Wei ◽  
Yujuan Wei ◽  
Luyi Chen
Keyword(s):  
Flame Retardant ◽  
Substitution Effect ◽  
Cotton Fabrics ◽  
Green Technology ◽  
Cleaner Production ◽  
Wastewater Discharge ◽  
One Step ◽  
And Performance ◽  
Time Required ◽  
Green Chemicals

Abstract There is a conflict between enhancing the functionality of products and reducing the environmental impact of manufacturing in the materials industry. Using green chemicals or adopting cleaner production processes can help overcome this conflict. However, researchers usually neglect the substitution effect when selecting green technology, namely, that investing more in chemical development decreases the resources used in cleaner process techniques. This study demonstrated this substitution effect in the modification of cotton fabrics. We fabricated hydrophobic and flame-retardant cotton fabrics with functional integrated graphene. It was found that these fabrics can be prepared in one step. As seen from an environmental assessment, applying functional integrated graphene can decrease the time required, reduce the energy consumption, and reduce the wastewater discharge. Based on the hydrophobicity-flame retardancy quadrant, we found that functional integrated graphene can improve the compatibility of different functionalities. On the other hand, compared to the use of commercial finishing agents, using functional integrated graphene can reduce organic discharge by up to 92%. This study demonstrates that using green chemicals can reduce pollution discharge and result in a cleaner production process. This study also provided atom economic ideas for green modification of cellulosic materials.

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