In this study, the phenomena of water droplet impact on burning methanol and n-heptane pool surfaces were experimentally investigated under various size and velocity conditions of impact droplet. In the n-heptane pool, the temperature increased to the deeper location of the pool and the droplet impact velocity was slower, as compared with those in the methanol pool. These results were caused by the higher heat release rate of the n-heptane pool. However, the impact droplet sizes on the burning methanol and n-heptane pool surfaces appeared to be similar. By visualizing the droplet impact phenomena, the impact pattern maps of burning methanol and n-heptane pool surfaces were constructed and compared with the previous impact pattern maps of their unburned pool surfaces. In the burning and unburned methanol and unburned n-heptane pools, patterns of single jet and splash with secondary jet were observed. On the contrary, in the burning n-heptane pool, patterns of single jet and canopy were observed.