Preparation and characterization of poly(methyl methacrylate) and poly(maleic anhydride-co-diallyl phthalate) grafted carbon black through γ-ray irradiation

In the reaction of dianions with poly(methyl methacrylate), only an insignificant amount of insoluble crosslinked product is obtained. If, however, the concentration of grafting dianions approaches that of ester groups, the amount of poly(methyl methacrylate) which may thus be crosslinked becomes quite significant. Dications, too, can bring about crosslinking of only an insignificant number of poly(methyl methacrylate) chains. Carboxylic groups in poly(acrylic acid) react with dianions and dications in an anhydrous medium similarly to ester groups. On the other hand, in the presence of a cocatalytic amount of water dications are more readily bound to carboxylic groups, forming a covalent bond. The relatively highest efficiency was observed in the bond formation between dication and the poly[styrene-alt-(maleic anhydride)], both in an anhydrous medium and in the presence of H2O.

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The synthesis, characterization of opal-poly(methyl methacrylate) graft polymer based on ICAR-ATRP and its effect on performance of poly (lactic acid)

Polymer-Plastics Technology and Materials ◽

10.1080/25740881.2021.1876878 ◽

2021 ◽

Vol 60 (10) ◽

pp. 1051-1065

Author(s):

Dawei Luo ◽

Gaowei Lei ◽

Weijun Zhen ◽

Ling Zhao

Keyword(s):

Lactic Acid ◽

Methyl Methacrylate ◽

Poly Lactic Acid ◽

Graft Polymer ◽

Poly Methyl Methacrylate

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Synthesis and Characterization of Poly(methyl methacrylate-block-ethylene glycol-block-methyl methacrylate) Block Copolymers by Reversible Addition-Fragmentation Chain Transfer Polymerization

Journal of Macromolecular Science Part A ◽

10.1080/10601325.2011.528310 ◽

2010 ◽

Vol 48 (1) ◽

pp. 65-70 ◽

Cited By ~ 23

Author(s):

Temel Öztürk ◽

Melahat Göktaş ◽

Bakí Hazer

Keyword(s):

Block Copolymers ◽

Ethylene Glycol ◽

Methyl Methacrylate ◽

Chain Transfer ◽

Synthesis And Characterization ◽

Poly Methyl Methacrylate ◽

Reversible Addition ◽

Chain Transfer Polymerization

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Detailed study on the characterization of silver nanocluster in poly(methyl methacrylate)

MRS Proceedings ◽

10.1557/proc-501-227 ◽

1997 ◽

Vol 501 ◽

Cited By ~ 3

Author(s):

Naohisa Yanagihara ◽

Kazutaka Uchida ◽

Muyuki Wakabayashi ◽

Toru Hara

Keyword(s):

Heat Treatment ◽

Methyl Methacrylate ◽

Treatment Duration ◽

Bulk Polymerization ◽

Visible Spectroscopy ◽

Poly Methyl Methacrylate ◽

Silver Nanocluster ◽

Ag Cluster ◽

Heat Treatment Duration

ABSTRACTSolid sol of silver in poly(methyl methacrylate), Ag/PMMA, was prepared by bulk polymerization of methyl methacrylate solution of silver (I) triflluoroacetate (AgTfa) and followed by postheating. The formation of the metallic Ag nanocluster was characterized by visible spectroscopy, and effects of the concentrations of AIBN and AgTfa and the heat-treatment duration on the formation of Ag cluster were investigated. Furthermore, based on the kinetic study of MMA in the presence of AgTfa, possible mechanism for the reduction and agglomeration of silver is proposed.

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