Temperature and pressure dependence of the mode Grüneisen parameters close to the melting point in hexagonal ice

Author(s):  
H. Karacali ◽  
H. Yurtseven
2010 ◽  
Vol 24 (19) ◽  
pp. 3749-3758
Author(s):  
E. KILIT ◽  
H. YURTSEVEN

We calculate in this study the volume of ice I as functions of temperature and pressure close to the melting point by analyzing the experimental data for the thermal expansivity. Using an approximate relation, the temperature dependence of the volume is calculated at 202.4 MPa from the thermal expansivity of ice I. The pressure dependence of the volume is also calculated at 252.3 K from the isothermal compressibility of ice I close to the melting point. The volume calculated here as functions of temperature and pressure shows critical behavior close to the melting point in ice I, which can be tested by the experimental measurements.


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