A series of phosphorescent Cu(I) complexes: Synthesis, photophysical feature and optical oxygen sensing performance in MCM-41 silica matrix

2016 ◽  
Vol 233 ◽  
pp. 347-354 ◽  
Author(s):  
Lu Guangying ◽  
Fang Jun
2014 ◽  
Vol 36 (9) ◽  
pp. 1542-1554 ◽  
Author(s):  
Xiao-yong Xu ◽  
Han-ning Xiao ◽  
Ai-ping Deng

2014 ◽  
Vol 585 ◽  
pp. 729-733 ◽  
Author(s):  
Linhui Gan ◽  
Congcong Wu ◽  
Yuan Tan ◽  
Bo Chi ◽  
Jian Pu ◽  
...  

2011 ◽  
Vol 364 ◽  
pp. 159-163
Author(s):  
Izza Taib Nurul ◽  
Salasiah Endud ◽  
M. Nasir Katun

A composite structure based on silylated MCM-41 and Poly (vinyl acetate) (PVAc) was synthesized via solution intercalation. Poly (vinyl acetate)-silylated Si-MCM-41 composite were characterized by XRD, FTIR spectroscopy and13C CP/MAS NMR in order to determine the compatibility between PVAc and the silicate host. XRD study reveals that the framework of silylated Si-MCM-41 was not altered upon incorporation of PVAc. FTIR study showed that characteristic peak assigned to carbonyl group in PVAc was observed around 1741.6 cm-1for all the composites indicating the presence of PVAc in the silylated Si-MCM-41.13C CP/MAS NMR showed the increase of line width of the peak assigned to C=O carbonyl group indicating the increase in randomness of polymer chains in confined space. The shifting of the C=O carbonyl groups is a sign of the change in chemical environment of the carbonyl owing to the interaction of PVAc with the silica matrix of silylated Si-MCM-41.


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