Determination of the diffusion coefficient of lithium ions in nano-Si

2009 ◽  
Vol 180 (2-3) ◽  
pp. 222-225 ◽  
Author(s):  
N. Ding ◽  
J. Xu ◽  
Y.X. Yao ◽  
G. Wegner ◽  
X. Fang ◽  
...  
2012 ◽  
Vol 66 ◽  
pp. 88-93 ◽  
Author(s):  
Shunyi Yang ◽  
Xianyou Wang ◽  
Xiukang Yang ◽  
Yansong Bai ◽  
Ziling Liu ◽  
...  

1996 ◽  
Vol 05 (01) ◽  
pp. 3-11 ◽  
Author(s):  
GÜLHAYAT NASÜN-SAYGILI ◽  
HASANCAN OKUTAN

1997 ◽  
Vol 496 ◽  
Author(s):  
M. Inaba ◽  
S. Nohmi ◽  
A. Funabiki ◽  
T. Abe ◽  
Z. Ogumi

ABSTRACTThe electrochemical permeation method was applied to the determination of the diffusion coefficient of Li+ion (DLi+) in a glassy carbon (GC) plate. The cell was composed of two compartments, which were separated by the GC plate. Li+ions were inserted electrochemically from one face, and extracted from the other. The flux of the permeated Li+ions was monitored as an oxidation current at the latter face. The diffusion coefficient was determined by fitting the transient current curve with a theoretical one derived from Fick's law. When the potential was stepped between two potentials in the range of 0 to 0.5 V, transient curves were well fitted with the theoretical one, which gaveDLi+ values on the order of 10−8cm2s−1. In contrast, when the potential was stepped between two potentials across 0.5 V, significant deviation was observed. The deviation indicated the presence of trap sites as well as diffusion sites for Li+ions, the former of which is the origin of the irreversible capacity of GC.


Sign in / Sign up

Export Citation Format

Share Document