A facile strategy to improve the cycle stability of 4.45 V LiCoO2 cathode in gel electrolyte system via succinonitrile additive under elevated temperature

2019 ◽  
Vol 341 ◽  
pp. 115049 ◽  
Author(s):  
Ning Xu ◽  
Hebing Zhou ◽  
Youhao Liao ◽  
Guanjie Li ◽  
Mengqing Xu ◽  
...  
2014 ◽  
Vol 1 (1) ◽  
pp. 26-35 ◽  
Author(s):  
Mrigank Dwivedi ◽  
◽  
Nidhi Asthana ◽  
Kamlesh Pandey

2009 ◽  
Vol 421-422 ◽  
pp. 467-470 ◽  
Author(s):  
Kazunori Nishiwaki ◽  
Takashi Ogihara ◽  
Shigeru Motohira ◽  
Takayuki Kodera

Spherical porous Mn2O3 powders were prepared by spray pyrolysis. Li and Al nitrate solution were immersed to porous Mn2O3 powders to obtain LiAlXMn2-XO4. Homogeneous LiAlXMn2-XO4 powders were formed by the calcination at 800°C. SEM observation showed that they had spherical morphology with particle size of about 1m. XRD revealed that the spinel phase was obtained by heating at 800°C. LiAlXMn2-XO4 cathode obtained by this method exhibited higher rechargeable capacity and cycle stability than that obtained by spray pyrolysis. The doping of Al ion was effective for the cycle stability at elevated temperature.


2013 ◽  
Vol 48 (4) ◽  
pp. 1606-1611 ◽  
Author(s):  
Ou Sha ◽  
Zhi Qiao ◽  
Shaoliang Wang ◽  
Zhiyuan Tang ◽  
Hao Wang ◽  
...  

2006 ◽  
Vol 517 ◽  
pp. 97-100 ◽  
Author(s):  
M.I.N. Isa ◽  
S.R. Majid ◽  
A.K. Arof

A gel electrolyte system was prepared by dissolving poly(methyl methacrylate) in ethylene carbonate and propylene carbonate doped with salicylic acid and plasticized with dibutylphthalate (DBP). The gel was heated to 70 0C before it was cast into glass dishes. The composition of the electrolytes was 35 wt% EC, 30 wt% PC, 5 wt% SA, 5wt% DBP and 25 wt% PMMA. The gel electrolyte was sandwiched between two stainless-steel blocking electrodes and impedance measurements were conducted. The conductivity of the gel electrolyte was 2.03 x 10-4 S cm-1 at room temperature. The conductivity activation energy was obtained from the log σ versus 103/T graph. Loss tangent was calculated at every frequency for all temperatures. From the tan δ versus frequency plot, the activation energy of relaxation of the ion was calculated and plotted as ln τ versus 103/T. The conductivity activation energy value was (0.21 ± 0.04) eV and the activation energy of relaxation was (0.24±0.07) eV. The similarity between these activation energies imply that the protons ‘hop’ from one electronegative oxygen site in DBP to another.


2009 ◽  
Vol 82 (6) ◽  
pp. 421-432 ◽  
Author(s):  
Sateesh Kumar Patel ◽  
Arvind Awadhia ◽  
S.L. Agrawal

RSC Advances ◽  
2014 ◽  
Vol 4 (104) ◽  
pp. 59981-59989 ◽  
Author(s):  
Laiying Jing ◽  
Aiping Fu ◽  
Hongliang Li ◽  
Jingquan Liu ◽  
Peizhi Guo ◽  
...  

Fe3O4/graphene composites with high reversible capacity and outstanding cycle stability were prepared within 6 h by a one-step high-temperature solvothermal process.


2018 ◽  
Vol 19 (1) ◽  
pp. 43-47 ◽  
Author(s):  
V.V. Klepko ◽  
◽  
V.I. Slisenko ◽  
K.M. Sukhyy ◽  
S.D. Nesin ◽  
...  

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