Emerging green solvents and their applications during pesticide analysis in food and environmental samples

Talanta ◽  
2021 ◽  
Vol 223 ◽  
pp. 121507
Author(s):  
Herbert Musarurwa ◽  
Nikita Tawanda Tavengwa
Author(s):  
Elham Sobhanzadeh ◽  
Nor Kartini Abu Bakar ◽  
Mhd Radzi Abas ◽  
Keivan Nemati

Much attention has been made in pesticide analysis to improve agricultural productivity and control these compounds in food and environmental samples. Different methods have been applied in pesticide analysis, among these; methods based on chromatographic separation with mass spectrometric detection have been extremely useful methods for determination of pesticide residues. Despite employing of powerful instrumental techniques, the risk of interference increases with the complexity of the matrix studied, so sample preparation prior to instrumental analysis is necessary. This article reviews the analytical characteristics of the different sample preparation methods for determination of pesticide residues in food and environmental samples and biological fluids, moreover this study describes advantages, disadvantages and details on the analytical characteristics of the procedure that have been applied recently in different sample preparation methods and their application s in combination with chromatographic mass spectrometric analysis. This article provides selection of a reliable method which will be useful for the quantitative analysis of pesticide residues in variety of samples based on their evaluation in recent applications.


Author(s):  
R. E. Ferrell ◽  
G. G. Paulson ◽  
C. W. Walker

Selected area electron diffraction (SAD) has been used successfully to determine crystal structures, identify traces of minerals in rocks, and characterize the phases formed during thermal treatment of micron-sized particles. There is an increased interest in the method because it has the potential capability of identifying micron-sized pollutants in air and water samples. This paper is a short review of the theory behind SAD and a discussion of the sample preparation employed for the analysis of multiple component environmental samples.


2018 ◽  
Vol 52 (2) ◽  
pp. 187-199 ◽  
Author(s):  
Aya Sakaguchi ◽  
Haruka Chiga ◽  
Kazuya Tanaka ◽  
Haruo Tsuruta ◽  
Yoshio Takahashi

2017 ◽  
Author(s):  
Jose A. Pomposo

Understanding the miscibility behavior of ionic liquid (IL) / monomer, IL / polymer and IL / nanoparticle mixtures is critical for the use of ILs as green solvents in polymerization processes, and to rationalize recent observations concerning the superior solubility of some proteins in ILs when compared to standard solvents. In this work, the most relevant results obtained in terms of a three-component Flory-Huggins theory concerning the “Extra Solvent Power, ESP” of ILs when compared to traditional non-ionic solvents for monomeric solutes (case I), linear polymers (case II) and globular nanoparticles (case III) are presented. Moreover, useful ESP maps are drawn for the first time for IL mixtures corresponding to case I, II and III. Finally, a potential pathway to improve the miscibility of non-ionic polymers in ILs is also proposed.


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