Influence of antioxidant on the thermal–oxidative degradation behavior and oxidation stability of synthetic ester

2014 ◽  
Vol 591 ◽  
pp. 16-21 ◽  
Author(s):  
Mianran Chao ◽  
Weimin Li ◽  
Xiaobo Wang
2015 ◽  
Vol 69 (7) ◽  
Author(s):  
Mian-Ran Chao ◽  
Wei-Min Li ◽  
Li-Li Zhu ◽  
Hai-Hong Ma ◽  
Xiao-Bo Wang

AbstractAn oil-soluble antioxidant, alkylated diphenylamine (ADPA), was prepared by alkylation of diphenylamine. The influence of ADPA on the thermal-oxidative stability of poly-α-olefin (PAO8) was evaluated by thermogravimetry (TG). For comparison, the thermal-oxidative stability of PAO8 with zinc dialkyl dithiophosphate (ZDDP) was also investigated. Activation energy (E


2015 ◽  
Vol 1088 ◽  
pp. 343-347
Author(s):  
Peng Wei ◽  
Shuo Han Huang ◽  
Yan Ping Wang ◽  
Yi Min Wang

In this study, the thermal oxidative degradation behavior of thermotropic liquid crystal copolyesters P-BPAFx containing 2.5-10 mol% bisphenol AF unit were evaluated by thermogravimetric analysis (TGA) technique under air atmosphere and the degradation activation energy (E) was obtained from Kissinger and Kissinger-Akahira-Sunose (KAS) method. The degradation behavior of copolyester are strongly dependent on the molar percentage of BPAF unit. Results showed that the E values obtained by the two methods increase first and then decrease slightly with increasing the BPAF unit and follow the order P-BPAF5.0< P-BPAF10<P-BPAF2.5, indicating P-BPAF2.5 has good thermal stability. The reason for this phenomenon was discussed in detail in the text.


1968 ◽  
Vol 10 (11) ◽  
pp. 2870-2879 ◽  
Author(s):  
V.V. Rode ◽  
Yu.P. Novichenko ◽  
S.R. Rafikov

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