Chiral titanium(IV) and vanadium(V) salen complexes as catalysts for carbon dioxide and epoxide coupling reactions

Tetrahedron ◽  
2021 ◽  
Vol 82 ◽  
pp. 131929
Author(s):  
Svetlana A. Kuznetsova ◽  
Ilia V. Gorodishch ◽  
Alexander S. Gak ◽  
Valeria V. Zherebtsova ◽  
Igor S. Gerasimov ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Coupling Reactions ◽  
Salen Complexes

Formation of Cyclic Carbonates from Carbon Dioxide and Epoxides Coupling Reactions Efficiently Catalyzed by Robust, Recyclable One-Component Aluminum-Salen Complexes

ACS Catalysis ◽  
2012 ◽  
Vol 2 (9) ◽  
pp. 2029-2035 ◽  
Author(s):  
Dawei Tian ◽  
Binyuan Liu ◽  
Quanying Gan ◽  
Huanrong Li ◽  
Donald. J. Darensbourg
Keyword(s):  
Carbon Dioxide ◽  
Coupling Reactions ◽  
Cyclic Carbonates ◽  
Salen Complexes

Salen ligand complexes as electrocatalysts for direct electrochemical reduction of gaseous carbon dioxide to value added products

RSC Advances ◽  
2015 ◽  
Vol 5 (5) ◽  
pp. 3581-3589 ◽  
Author(s):  
Surya Singh ◽  
Bedika Phukan ◽  
Chandan Mukherjee ◽  
Anil Verma
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Value Added ◽  
Salen Complexes ◽  
Gaseous Carbon Dioxide ◽  
Salen Ligand ◽  
Centrosymmetric Molecule ◽  
Value Added Products

CO2, being a linear and centrosymmetric molecule, is very stable, and the electrochemical reduction of CO2 requires energy. However, the salen complexes are found to be very efficient to minimize overpotential as compared to their metal counterparts.

Coupling Reactions of Carbon Dioxide with Epoxides Catalyzed by Vanadium Aminophenolate Complexes

ChemSusChem ◽  
2017 ◽  
Vol 10 (6) ◽  
pp. 1249-1254 ◽  
Author(s):  
Ali I. Elkurtehi ◽  
Francesca M. Kerton
Keyword(s):  
Carbon Dioxide ◽  
Coupling Reactions

Oxadiazoline and Ketoimine Palladium(II) Complexes as Highly Efficient Catalysts for Suzuki-Miyaura Cross-Coupling Reactions in Supercritical Carbon Dioxide

2011 ◽  
Vol 353 (7) ◽  
pp. 1153-1160 ◽  
Author(s):  
Ricardo R. Fernandes ◽  
Jamal Lasri ◽  
M. Fátima C. Guedes da Silva ◽  
António M. F. Palavra ◽  
José A. L. da Silva ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Highly Efficient ◽  
Cross Coupling Reactions ◽  
Supercritical Carbon

Copolymerization of Carbon Dioxide and Propylene Oxide Catalyzed by Salen Complexes

2013 ◽  
Vol 734-737 ◽  
pp. 2159-2162 ◽  
Author(s):  
Chong Wen Jiang ◽  
Chen Chen Zhao ◽  
Ke Yuan Zhou
Keyword(s):  
Carbon Dioxide ◽  
1H Nmr ◽  
Propylene Oxide ◽  
Great Influence ◽  
Carbonate Content ◽  
Central Metal ◽  
Salen Complexes ◽  
Metal Atoms ◽  
Ft Ir

Three salen complexes N,N'-bis(salicylidene)-1,2-phenylenediamino MⅢ Cl were prepared and employed for the copolymerization of carbon dioxide with propylene oxide. FT-IR and UV-Vis spectra confirmed the characteristic of metal salen complexes obtained. The central metal atoms in the salen complexes have great influence on the copolymerization of carbon dioxide with propylene oxide. The result shows that chromium metal is more effective to synthesize PPC copolymer. The structure of the resulting PPC was characterized by IR 1H NMR and GPC. 86.3% carbonate content of the PPC was achieved with chromium salen complexes.

Synthesis of Heterobimetallic RuMn Complexes and the Coupling Reactions of Epoxides with Carbon Dioxide Catalyzed by these Complexes

2006 ◽  
Vol 12 (4) ◽  
pp. 1004-1015 ◽  
Author(s):  
Man Lok Man ◽  
King Chung Lam ◽  
Wing Nga Sit ◽  
Siu Man Ng ◽  
Zhongyuan Zhou ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Coupling Reactions
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