A highly efficient reusable homogeneous copper catalyst for the selective aerobic oxygenation sulfides to sulfoxides

The efficient electroreduction reaction of nitrate (NO3-RR) at low concentrations to ammonia is energetically favorable for ammonia production and environmentally essential to treat water contamination. Copper-based conjugated molecule electrocatalysts for...

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Supported ionic liquid-copper catalyst for synergistically catalytic and highly efficient hydration of acetylene

International Journal of Hydrogen Energy ◽

10.1016/j.ijhydene.2021.12.163 ◽

2022 ◽

Author(s):

Qiang Zhang ◽

Xiejie Chen ◽

Yu Xie ◽

Xinyue Ji ◽

Qihong An ◽

...

Keyword(s):

Ionic Liquid ◽

Liquid Copper ◽

Copper Catalyst ◽

Supported Ionic Liquid ◽

Highly Efficient

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Highly Efficient Heterogeneous Copper-Catalysed O-Arylation of Phenols by Nitroarenes Leading to Diaryl Ethers

Journal of Chemical Research ◽

10.3184/174751917x15122516000113 ◽

2017 ◽

Vol 41 (12) ◽

pp. 725-729 ◽

Cited By ~ 1

Author(s):

Yingying Du ◽

Fang Yao ◽

Yuxin Tuo ◽

Mingzhong Cai

Keyword(s):

Copper Catalyst ◽

Simple Procedure ◽

Significant Loss ◽

Diaryl Ethers ◽

Highly Efficient ◽

Reaction Solution ◽

Mcm 41

The heterogeneous O-arylation of phenols by nitroarenes was achieved in DMF at 100 °C by using an MCM-41-immobilised bidentate nitrogen copper(II) complex [MCM-41-2N-Cu(OAc)2] as catalyst, yielding a variety of unsymmetrical diaryl ethers in good to excellent yields. This heterogeneous copper catalyst can be easily prepared by a simple procedure from commercially readily available and inexpensive reagents, recovered by filtration of the reaction solution and recycled at least seven times without significant loss of activity.

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Highly efficient and practical aerobic oxidation of alcohols by inorganic-ligand supported copper catalysis

Green Chemistry ◽

10.1039/c9gc01248f ◽

2019 ◽

Vol 21 (15) ◽

pp. 4069-4075 ◽

Cited By ~ 10

Author(s):

Zheyu Wei ◽

Shi Ru ◽

Qixin Zhao ◽

Han Yu ◽

Gang Zhang ◽

...

Keyword(s):

Copper Catalyst ◽

Aerobic Oxidation ◽

Copper Catalysis ◽

Inorganic Ligand ◽

Highly Efficient ◽

Oxidation Of Alcohols ◽

Supported Copper Catalyst ◽

Excellent Selectivity

An inorganic-ligand supported copper catalyst which can effectively catalyze the aerobic oxidation of alcohols to afford aldehydes or ketones with excellent selectivity and yields.

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Nitrogen-doped carbon-decorated copper catalyst for highly efficient transfer hydrogenolysis of 5-hydroxymethylfurfural to convertibly produce 2,5-dimethylfuran or 2,5-dimethyltetrahydrofuran

Applied Catalysis B Environmental ◽

10.1016/j.apcatb.2018.01.006 ◽

2018 ◽

Vol 226 ◽

pp. 523-533 ◽

Cited By ~ 66

Author(s):

Zhi Gao ◽

Chenyue Li ◽

Guoli Fan ◽

Lan Yang ◽

Feng Li

Keyword(s):

Copper Catalyst ◽

Nitrogen Doped ◽

Highly Efficient ◽

Nitrogen Doped Carbon ◽

Efficient Transfer

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A Highly Efficient Heterogeneous Copper-Catalyzed Oxidative Cyclization of Benzylamines and 1,3-Dicarbonyl Compounds To Give Trisubstituted Oxazoles

Synthesis ◽

10.1055/s-0037-1610710 ◽

2019 ◽

Vol 51 (16) ◽

pp. 3091-3100

Author(s):

Li Wei ◽

Shengyong You ◽

Yuxin Tuo ◽

Mingzhong Cai

Keyword(s):

Copper Catalyst ◽

Oxidative Cyclization ◽

Dicarbonyl Compounds ◽

Mild Conditions ◽

Highly Efficient ◽

Intermolecular Cyclization ◽

Step Procedure ◽

Mcm 41

The heterogeneous copper-catalyzed cascade oxidative cyclization between benzylamines and 1,3-dicarbonyl compounds was achieved by using the 3-(2-aminoethylamino)propyl-functionalized MCM-41-immobilized copper(II) complex [MCM-41-2N-Cu(OAc)2] as catalyst and t-BuOOH (TBHP) as oxidant, with iodine as additive, under mild conditions, yielding a wide variety of 2,4,5-trisubstituted oxazoles in mostly good to excellent yields. This heterogeneous copper catalyst can be facilely prepared via a simple two-step procedure from readily available and inexpensive reagents and exhibits a slightly higher activity than Cu(OAc)2. MCM-41-2N-Cu(OAc)2 is also easy to recover and can be recycled up to eight times with almost consistent activity. The reaction is the first example of heterogeneous copper-catalyzed intermolecular cyclization for the construction of polysubstituted oxazoles.

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Efficient Heterogeneous Copper-Catalysed C–Se Coupling of Aryl Iodides with Symmetrical Diselenides towards Unsymmetrical Monoselenides

Journal of Chemical Research ◽

10.3184/174751918x15409874473285 ◽

2018 ◽

Vol 42 (11) ◽

pp. 584-588 ◽

Cited By ~ 1

Author(s):

Ruonan Zhao ◽

Chenyu Yan ◽

Yuanyuan Jiang ◽

Mingzhong Cai

Keyword(s):

Copper Catalyst ◽

Significant Loss ◽

Highly Efficient ◽

Aryl Iodides ◽

Reaction Solution ◽

Simple Filtration ◽

Neutral Conditions ◽

Mcm 41

A highly efficient heterogeneous copper(I)-catalysed C–Se coupling of aryl iodides with diaryl diselenides was achieved in dimethylformamide at 110 °C under neutral conditions by using a 10 mol% of bipyridine-functionalised MCM-41-supported copper(I) complex [bpy-MCM-41-CuI] as the catalyst and magnesium as the reductive reagent, yielding a variety of unsymmetrical diaryl selenides in good to excellent yields. This heterogeneous copper catalyst can be easily recovered by a simple filtration of the reaction solution and recycled at least seven times without significant loss of activity.

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