Using Fly Ash Wastes for the Development of New Building Materials with Improved Compressive Strength

Fly ash wastes (silica, aluminum and iron-rich materials) could be smartly valorized by their incorporation in concrete formulation, partly replacing the cement. The necessary binding properties can be accomplished by a simple procedure: an alkali activation process, involving partial hydrolysis, followed by gel formation and polycondensation. The correlations between the experimental fly ash processing conditions, particle characteristics (size and morphology) and the compressive strength values of the concrete prepared using this material were investigated by performing a parametric optimization study to deduce the optimal processing set of conditions. The alkali activation procedure included the variation of the NaOH solutions concentration (8–12 M), temperature values (25–65 °C) and the liquid/solid ratio (1–3). The activation led to important modifications of the crystallography of the samples (shown by powder XRD analysis), their morphologies (seen by SEM), particle size distribution and Blaine surface values. The values of the compressive strength of concrete prepared using fly ash derivatives were between 16.8–22.6 MPa. Thus, the processed fly ash qualifies as a proper potential building material, solving disposal-associated problems, as well as saving significant amounts of cement consumed in concrete formulation.

Novel Foaming-Agent Free Insulating Geopolymer Based on Industrial Fly Ash and Rice Husk

This study highlights the synthesis of a new thermal insulating geopolymer based on the alkaline activation of fly ashes. A porous geopolymer material can be prepared without the addition of a foaming agent, using high ratio solution/ashes (activating solutions used are water, sodium or potassium hydroxide). In order to increase the porosity of the material and to make it more ecological, rice husks are incorporated into the formulation. The geopolymer materials were prepared at room temperature and dried at moderate temperature (105 °C) by a simple procedure. The microstructural characteristics of these new porous geopolymers were assessed by optical microscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA) and X-ray fluorescence (XRF). Infrared spectroscopy (FTIR) was used to confirm the geopolymerisation. The effect of the ratio solution/ashes and the percentage of the rice husk addition on thermal and mechanical analysis was evaluated. An insulating material for a solution/ashes ratio of 0.9 and a rice husk content of 15% having a λ value of 0.087 W/(m·K), a porosity of 61.4% and an Rc value of 0.1 MPa was successfully prepared.

Application of a Thermal Performance-Based Model to Prediction Energy Consumption for Heating of Single-Family Residential Buildings

Energy consumption for heating of single-family residential buildings is a basic item in energy balance and significantly affects their operating costs. Accuracy of heat consumption assessment in existing buildings to a large extent determines the decision on taking actions aimed at heat consumption rationalization, both at the level of a single building and at regional or national level. In the case of energy calculations for the existing buildings, a problem often arises in the form of lack of complete architectural and construction documentation of the analyzed objects. Therefore, there is a need to search for methods that will be suitable for rapid energy analysis in existing buildings. These methods should give satisfactory results in predicting energy consumption when there is limited access to data characterizing the building. Therefore, the aim of this study was to check the usefulness of a model based on thermal characteristics for estimating energy consumption for heating in single-family residential buildings. The research was conducted on a group of 84 buildings, for which the energy characteristics were determined based on the actual energy consumption. In addition, information was collected on variables describing these buildings in terms of construction technology and building geometry, from which the following were extracted for further calculations: cubic capacity, heated area, and year of construction. This made it possible to build a prediction model, which enables the application of a fast, relatively simple procedure of estimating the final energy demand index for heating buildings. The resulting calculations were compared with actual values (calculated from energy bills) and then evaluated according to the standards for evaluating model quality proposed by the American Society of Heating, Refrigerating, and Air-Conditioning Engineers (ASHRAE). In this way, it was possible to determine whether, in the absence of building documents, the indicative method gives good results when estimating the energy demand for heating single-family residential buildings.

Ureteric Rupture: Rare Complication of Inappropriate Urinary Bladder Catheterization

We have reported case of 71-year-old male with acute urinary retention due to gross prostatomegaly. Due to inappropriate catheterization, urinary bladder remained distended and ultimately caused left ureteric rupture. This article is peculiar as it shows that misplaced Foley's catheter may also lead to exceedingly rare complication of ureteric rupture and highlights importance of proper management of difficult catheterization which is otherwise considered a simple procedure.

Evaluation of Kinetic Pseudo-Order in the Photocatalytic Degradation of Ofloxacin

Ofloxacin is a highly efficient and widely used antibiotic drug. It is classified as a refractory pollutant due to its poor biodegradability. Consequently, it is commonly found in water sources, requiring efficient methods for its removal. Advanced oxidation processes (AOPs) offer efficient alternatives since those yield complete degradation not achieved in adsorption or membrane processes. Previous studies suggest ofloxacin degradation follows a pseudo-first or -second order processes, whereas for full removal of refractory pollutants—lower pseudo-orders are required. Monitoring the actual “pseudo-order” degradation kinetics of ofloxacin is needed to evaluate any proposed AOP process. This study presents a simple procedure to evaluate pseudo-orders of AOPs. Photolysis of 20 μM ofloxacin solutions follow pseudo-zero order kinetics, with half-life times (t1/2) of approx. 60 min. TiO2 heterogenous catalysts have been shown to have no influence at low concentrations (0.2 mg L−1), but a significant reduction of half-life time (t1/2 = 20 min) and increase in pseudo-order (0.8) is measured at 2.0 mg L−1. Similar results are obtained with homogenous catalysis by 2.0 mg L−1 H2O2. The combination of H2O2 and TiO2 catalysts shows additional reduction in half-time life with increase in the pseudo-order to 1.2. The conclusions are (1) heterogenous and homogenous photocatalysis can effectively degrade ofloxacin, (2) combined photocatalysis yields higher pseudo-order, being less prone to achieve full removal, and (3) analysis of specific pseudo-orders in AOPs of refractory pollutants helps to further elucidate the efficiency of the processes.

Nickel-Catalyzed Defluorinative Coupling of Aliphatic Aldehydes with Trifluoromethyl Styrenes

A simple procedure is reported for the nickel-catalyzed defluorinative alkylation of unactivated aliphatic aldehydes. The process involves the catalytic reductive union of trifluoromethyl styrenes with aldehydes using a nickel complex of a 6,6’-disubstituted bipyridine ligand with zinc metal as the terminal reductant. The protocol is distinguished by its broad substrate scope, mild conditions, and simple catalytic setup. Reaction outcomes are consistent with the intermediacy of an alpha-silyloxy(alkyl)nickel intermediate generated by a low-valent nickel catalyst, silyl electrophile, and the aldehyde substrate. Mechanistic findings with cyclopropanecarboxaldehyde provide insights into nature of the reactive intermediates and illustrate fundamental reactivity differences that are governed by subtle changes in ligand and substrate structure.

Evaluation of Kinetic Pseudo-Order in the Photocatalytic Degradation of Oflaxicin

Ofloxacin is a highly efficient and widely used antibiotic drug. It is classified as a refractory pollutant due to its poor biodegradability. Consequently, it is commonly found in water sources, requiring efficient methods for its removal. Advanced Oxidation Processes (AOPs) offer efficient alternatives since those yield complete degradation not achieved in adsorption or membrane processes. Previous studies suggest ofloxacin degradation follows a pseudo-first or -second order processes, whereas for full removal of refractory pollutants – lower pseudo-orders are required. Monitoring the actual “pseudo-order” degradation kinetics of ofloxacin is needed to evaluate any proposed AOP process. This study presents a simple procedure to evaluate pseudo-orders of AOPs. Photolysis of 20 mM ofloxacin solutions follow pseudo-zero order kinetics, with half-life times (t1/2) of approx. 60 min. TiO2 heterogenous catalyst show to have no influence at low concentration (0.2 mg L-1) but a significant reduction of half-life time (t1/2 = 20 min) and increase in pseudo-order (0.8) is measured at 2.0 mg L-1. Similar results are obtained with homogenous catalysis by 2.0 mg L-1 H2O2. The combination of H2O2 and TiO2 catalysts shows additional reduction in half-time life with increase in the pseudo-order to 1.2. The conclusions are (1) heterogenous and homogenous photocatalysis can effectively degrade ofloxacin, (2) combined photocatalysis yields higher pseudo-order, being less prone to achieve full removal, (3) analysis of specific pseudo-orders in AOPs of refractory pollutants helps to further elucidate the efficiency of the processes.

Experimental Evaluation of Tension and Shear Responses of Material Discontinuities in Origami-Based Sheet Metal Bending

Origami-based sheet metal (OSM) bending uses the origami concept to form a three-dimensional (3D) structures from a two-dimensional (2D) sheet by a series of bending operation. The OSM bending relies on a material discontinuity (MD) to perform the bending operation where the MDs are subjected to tension and shear load. Even though the OSM bending is a process that is simple, cost-effective, and easy to integrate into mass production, the understanding of the OSM bending mechanics is limiting its wide application. Particularly, the deformation behavior of MDs under tension and shear load remains unknown. Hence, this work investigates the response of MDs to these loads using the standard tension and shear tests. From the tests, critical values for two different ductile fracture criteria (DFC) are determined, and the possibility of a failure occurring in OSM bending is predicted. Results show that the load-bearing capability of the MDs is related to change in the effective cross-section area of a MD. Simple tension and shear tests can provide a simple procedure to predict failure in OSM bending. The impact of self-contact occurred under shear load influences maximum shear force and accuracy of failure prediction.

Random sampling of the Protein Data Bank: RaSPDB

A novel and simple procedure (RaSPDB) for Protein Data Bank mining is described. 10 PDB subsets, each containing 7000 randomly selected protein chains, are built and used to make 10 estimations of the average value of a generic feature F—the length of the protein chain, the amino acid composition, the crystallographic resolution, and the secondary structure composition. These 10 estimations are then used to compute an average estimation of F together with its standard error. It is heuristically verified that the dimension of these 10 subsets—7000 protein chains—is sufficiently small to avoid redundancy within each subset and sufficiently large to guarantee stable estimations amongst different subsets. RaSPDB has two major advantages over classical procedures aimed to build a single, non-redundant PDB subset: a larger fraction of the information stored in the PDB is used and an estimation of the standard error of F is possible.

A cationic surfactant-decorated liquid crystal-based sensor for sensitive detection of quinoline yellow

Quinoline yellow (QY) is one of the popular synthetic food colorants and in food industry greatly used. Developing accurate and simple QY detection procedures is of major considerable importance in ensuring food safety. Hence, it is important to detect this food colorant effectively to reduce risk. Herein, an innovative liquid crystal (LC)-based sensor was designed for the label-free and ultra-sensitive detecting of the QY by means of a cationic surfactant-decorated LC interface. The nematic liquid crystal in touch with CTAB revealed a homeotropic alignment, when QY was injected into the LC-cell, the homeotropic alignment consequently altered to a planar one by electrostatic interactions between QY and CTAB. The designed LC-based sensor detected QY at the too much trace level as low as 0.5 fM with analogous selectivity. The suggested LC-based sensor is a rapid, convenient and simple procedure for label-free detection of QY in food industrial and safety control application.