Morpholinoethanesulfonic acid-based buffer system for improved detection limit and stability of the fluoride ion selective electrode

2003 ◽  
Vol 478 (1) ◽  
pp. 77-84 ◽  
Author(s):  
M Fouskaki ◽  
S Sotiropoulou ◽  
M Kočı́ ◽  
N.A Chaniotakis
1987 ◽  
Vol 33 (2) ◽  
pp. 253-255 ◽  
Author(s):  
E Kissa

Abstract Inorganic fluoride in whole blood, serum, or plasma has been determined with a fluoride ion-selective electrode by adding the 0.5- to 2.0-mL sample to 20 mL of water containing a buffer and fluoride, 25 micrograms/L. The fluoride concentration in the sample is calculated from the resulting cell potential difference recorded after equilibrating for 10 min. This novel method has the advantages of simplicity, accuracy, and high precision, standard deviations for 5 to 7 replicate determinations of fluoride ranging from +/- 1.7 to +/- 2.4 micrograms/L. For whole blood from donors living in an area with fluorinated drinking water, the F- concentration was 20 to 60 micrograms/L.


2007 ◽  
Vol 95 (10) ◽  
Author(s):  
R. M. Sawant ◽  
M. A. Mahajan ◽  
Poonam Verma ◽  
Dipti Shah ◽  
U. K. Thakur ◽  
...  

The determination of fluoride from diverse matrices at front and back end of nuclear technology and some studies from this laboratory on optimizations of different experimental parameters differing with multiple fuels and reactor materials, have been reviewed. The most useful techniques such as fluoride ion selective electrode (F-ISE) and ion-chromatography (IC) widely adopted as routine methods for fluoride determination in nuclear industry have been discussed. The effect of various buffer strengths on the response of the fluoride ion selective electrode has been examined. The ion chromatographic studies on mobile phase concentration, medium of sample, sample injection volume


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