Electronic interactions in metal complexed photoconducting polymers: a ZINDO study

2000 ◽  
Vol 331 (2-4) ◽  
pp. 299-307 ◽  
Author(s):  
Eric S Manas ◽  
Lin X Chen
2019 ◽  
Author(s):  
Shuyuan Zheng ◽  
Taiping Hu ◽  
Xin Bin ◽  
Yunzhong Wang ◽  
Yuanping Yi ◽  
...  

Pure organic room temperature phosphorescence (RTP) and luminescence from nonconventional luminophores have gained increasing attention. However, it remains challenging to achieve efficient RTP from unorthodox luminophores, on account of the unsophisticated understanding of the emission mechanism. Here we propose a strategy to realize efficient RTP in nonconventional luminophores through incorporation of lone pairs together with clustering and effective electronic interactions. The former promotes spin-orbit coupling and boost the consequent intersystem crossing, whereas the latter narrows energy gaps and stabilizes the triplets, thus synergistically affording remarkable RTP. Experimental and theoretical results of urea and its derivatives verify the design rationale. Remarkably, RTP from thiourea solids with unprecedentedly high efficiency of up to 24.5% is obtained. Further control experiments testify the crucial role of through-space delocalization on the emission. These results would spur the future fabrication of nonconventional phosphors, and moreover should advance understanding of the underlying emission mechanism.<br>


2021 ◽  
pp. 100919
Author(s):  
Zied Othmen ◽  
Riadh Othmen ◽  
Kais Daoudi ◽  
Michel Boudard ◽  
Antonella Cavanna ◽  
...  

Author(s):  
Jay Chuang ◽  
Chun‐Wei Chang ◽  
Yuan Jay Chang ◽  
Po‐Ting Chou ◽  
Yuh‐Sheng Wen ◽  
...  

2021 ◽  
Vol 2021 (1) ◽  
Author(s):  
András L. Szabó ◽  
Bitan Roy

Abstract We compute the effects of strong Hubbardlike local electronic interactions on three-dimensional four-component massless Dirac fermions, which in a noninteracting system possess a microscopic global U(1) ⊗ SU(2) chiral symmetry. A concrete lattice realization of such chiral Dirac excitations is presented, and the role of electron-electron interactions is studied by performing a field theoretic renormalization group (RG) analysis, controlled by a small parameter ϵ with ϵ = d−1, about the lower-critical one spatial dimension. Besides the noninteracting Gaussian fixed point, the system supports four quantum critical and four bicritical points at nonvanishing interaction couplings ∼ ϵ. Even though the chiral symmetry is absent in the interacting model, it gets restored (either partially or fully) at various RG fixed points as emergent phenomena. A representative cut of the global phase diagram displays a confluence of scalar and pseudoscalar excitonic and superconducting (such as the s-wave and p-wave) mass ordered phases, manifesting restoration of (a) chiral U(1) symmetry between two excitonic masses for repulsive interactions and (b) pseudospin SU(2) symmetry between scalar or pseudoscalar excitonic and superconducting masses for attractive interactions. Finally, we perturbatively study the effects of weak rotational symmetry breaking on the stability of various RG fixed points.


2000 ◽  
Vol 33 (38) ◽  
pp. 6779-6789 ◽  
Author(s):  
Shi-Jian Gu ◽  
You-Quan Li ◽  
Hai-Qing Lin

1977 ◽  
Vol 50 (7) ◽  
pp. 1665-1669 ◽  
Author(s):  
Tsutomu Mimura ◽  
Michiya Itoh ◽  
Toshiaki Ohta ◽  
Toshihiko Okamoto

2017 ◽  
Vol 19 (18) ◽  
pp. 4810-4813 ◽  
Author(s):  
Laura Rodríguez-Pérez ◽  
Sonia Vela ◽  
Carmen Atienza ◽  
Nazario Martín

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