High-temperature neutron powder diffraction study of the structural phase transition between α and α′ phases in tricalcium phosphate Ca3(PO4)2

2003 ◽  
Vol 372 (5-6) ◽  
pp. 779-783 ◽  
Author(s):  
Masatomo Yashima ◽  
Atsushi Sakai
2000 ◽  
Vol 154 (2) ◽  
pp. 524-529 ◽  
Author(s):  
K. Oikawa ◽  
T. Kamiyama ◽  
T. Hashimoto ◽  
Y. Shimojyo ◽  
Y. Morii

2001 ◽  
Vol 16 (4) ◽  
pp. 227-230 ◽  
Author(s):  
S. A. Ivanov ◽  
R. Tellgren ◽  
H. Rundlo¨f ◽  
V. G. Orlov

A detailed neutron powder diffraction study of the atomic structure of α-Bi2O3at high temperatures using the Rietveld method was performed to clarify the nature of the unusual magnetic behavior and the origin of the high temperature dielectric anomalies of α-Bi2O3in the temperature interval 300–700 K. Analysis of obtained experimental data shows that there are no evidence of a structural phase transition in α-Bi2O3between 295 and 660 K. The observed high temperature dielectric anomalies in α-Bi2O3are evidently governed by changes in the electron subsystem of the bismuth oxide.


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