Electrostatic Gibbs free energy of solvation from gas chromatographic data

1984 ◽  
Vol 284 ◽  
pp. 238-241 ◽  
Author(s):  
János Liszi ◽  
Béla Németh
1998 ◽  
Vol 102 (46) ◽  
pp. 9308-9308 ◽  
Author(s):  
Michael D. Tissandier ◽  
Kenneth A. Cowen ◽  
Wan Yong Feng ◽  
Ellen Gundlach ◽  
Michael H. Cohen ◽  
...  

Carbon ◽  
2009 ◽  
Vol 47 (12) ◽  
pp. 2865-2874 ◽  
Author(s):  
Patrick S. Redmill ◽  
Shannon L. Capps ◽  
Peter T. Cummings ◽  
Clare McCabe

2019 ◽  
Vol 21 (25) ◽  
pp. 13706-13720 ◽  
Author(s):  
Tohid N. Borhani ◽  
Salvador García-Muñoz ◽  
Carla Vanesa Luciani ◽  
Amparo Galindo ◽  
Claire S. Adjiman

QSPR models predict the Gibbs free energy of solvation of organic solute/solvent pairs by combining quantum mechanical and experimental descriptors.


2013 ◽  
Vol 15 (32) ◽  
pp. 13578 ◽  
Author(s):  
Matthew J. McGrath ◽  
I-F. Will Kuo ◽  
Brice F. Ngouana W. ◽  
Julius N. Ghogomu ◽  
Christopher J. Mundy ◽  
...  

1998 ◽  
Vol 102 (40) ◽  
pp. 7787-7794 ◽  
Author(s):  
Michael D. Tissandier ◽  
Kenneth A. Cowen ◽  
Wan Yong Feng ◽  
Ellen Gundlach ◽  
Michael H. Cohen ◽  
...  

Author(s):  
Dennis Sherwood ◽  
Paul Dalby

Building on the previous chapter, this chapter examines gas phase chemical equilibrium, and the equilibrium constant. This chapter takes a rigorous, yet very clear, ‘first principles’ approach, expressing the total Gibbs free energy of a reaction mixture at any time as the sum of the instantaneous Gibbs free energies of each component, as expressed in terms of the extent-of-reaction. The equilibrium reaction mixture is then defined as the point at which the total system Gibbs free energy is a minimum, from which concepts such as the equilibrium constant emerge. The chapter also explores the temperature dependence of equilibrium, this being one example of Le Chatelier’s principle. Finally, the chapter links thermodynamics to chemical kinetics by showing how the equilibrium constant is the ratio of the forward and backward rate constants. We also introduce the Arrhenius equation, closing with a discussion of the overall effect of temperature on chemical equilibrium.


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