The determination of inner sphere vibrational potential energy functions and the specification of thermodynamic states for the electron transfer reaction

1977 ◽  
Vol 82 (1-2) ◽  
pp. 29-63 ◽  
Author(s):  
P.P. Schmidt
Keyword(s):  
Electron Transfer ◽  
Potential Energy ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Energy Functions ◽  
Potential Energy Functions ◽  
Inner Sphere

Possible use of chronopotentiometry at the interface between two immiscible liquid phases to the studies of homogeneous chemical reactions

1985 ◽  
Vol 50 (8) ◽  
pp. 1636-1641
Author(s):  
Emanuel Makrlík
Keyword(s):  
Electron Transfer ◽  
Chemical Reactions ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Immiscible Liquid ◽  
Liquid Phases ◽  
Homogeneous Chemical ◽  
The Given ◽  
Galvanostatic Conditions

The theoretical potential-time dependence corresponding to the electron transfer reaction proceeding at the interface between two immiscible liquid phases with the redox pairs O1/R1 in the aqueous (aq) phase and O2/R2 in the non-aqueous (non) phase, that is complicated by the reaction R1(aq) + Z(aq) → O1(aq) in the aqueous phase, has been derived under the galvanostatic conditions. Moreover, a method for the determination of the formal rate constant kf for the given homogeneous chemical reaction is proposed.

Determination of electrochemical heterogeneous electron-transfer reaction rates from steady-state measurements at ultramicroelectrodes

1986 ◽  
Vol 58 (14) ◽  
pp. 2961-2964 ◽  
Author(s):  
Andrea. Russell ◽  
Kari. Repka ◽  
Timothy. Dibble ◽  
Jamal. Ghoroghchian ◽  
Jerry J. Smith ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Steady State ◽  
Transfer Reaction ◽  
Reaction Rates ◽  
Electron Transfer Reaction ◽  
Heterogeneous Electron Transfer
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