Note on approximate equations of DC polarographic current-potential curves for a catalytic wave

1982 ◽  
Vol 134 (1) ◽  
pp. 171-176 ◽  
Author(s):  
Chizuko Nishihara
Author(s):  
Gabriel Ybarra ◽  
Carlos Moina ◽  
María Inés Florit ◽  
Dionisio Posadas

<p class="PaperAbstract"><span lang="EN-US">In this work, the mediated reduction and oxidation of Fe(CN)<sub>6</sub><sup>3-/4-</sup> and Fe<sup>3+ </sup>in poly(o-aminophenol) coated electrodes is analyzed by means of diagnosis diagram based on the features of steady state current-potential curves. This analysis allows to identify the current determining process and to reproduce the experimental characteristics of the polarization curve from the relevant kinetic and thermodynamical parameters with a minimum amount of experimental measurements. </span></p>


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