The electrochemical behavior of 8-oxyquinoline and chelate complexes based on it (Sn (Oxin)Cl3, Ge (Oxin)Cl3, Ti (Oxin)Cl3, W(Oxin)2Cl4, Fe (Oxin)Br, Sb (Oxin)Cl2, Sb (Oxin)Cl4, Sn (Oxin)2Cl2, Ti (Oxin)2Cl2 have been studied by cyclic voltammetry in aprotic solvents in a three-electrode system on platinum and glass-graphite disk electrodes. It has been shown that in the case of metal oxyquinolinates, the ligand is 8-oxyquinoline reducing in two one-electron diffusion waves. The first wave is observed at less negative potentials than the first quinoline one, while the second waves have almost the same potentials. The first wave is related to the OH- proton discharge.
The complexes under study are electrolytically oxidizable. A single two-electron peak is observed in the cyclic voltammogram in the anodic region for the Ti (Oxin)Cl3 chelate complex. This is probably associated with two irreversible sequential or parallel stages with close oxidation potentials. By analogy to the processes considered for 8-oxyquinoline, the rupture of the oxygen-metal bond is observed at the first stage. The resulting radical cation is unstable and decomposes into a radical and a cation with a positive charge in the titanium atom. Electrolytic oxidation of complexes Fe (Oxin)Br, Sb (Oxin)Cl2, Sb (Oxin)Cl4, and Sn (Oxin)2Cl2 is similar to that of Ti (Oxin)Cl3.
Interactive Competition Between Individual Diffusion Layers during Cyclic Voltammetry at Random Arrays of Band and Disk Electrodes: A Thorough Analysis Based on Global Simulations
