Reaction chemistry, NMR spectroscopy, and X-ray crystallography of [Fe2(μ-SiMe2)2(CO)4] and [Fe2(μ-SiMeCl)2(CO)4]. Electronic structure and bonding in Fe2E2 rings of [Fe2(μ-ER2)2(CO)4] binuclear complexes (E=C, Si, Ge, Sn, Pb)

2001 ◽  
Vol 628 (2) ◽  
pp. 241-254 ◽  
Author(s):  
Richard S Simons ◽  
Kevin J Galat ◽  
John D Bradshaw ◽  
Wiley J Youngs ◽  
Claire A Tessier ◽  
...  
1991 ◽  
Vol 30 (25) ◽  
pp. 4743-4753 ◽  
Author(s):  
Saeed. Attar ◽  
Graham A. Bowmaker ◽  
Nathaniel W. Alcock ◽  
James S. Frye ◽  
William H. Bearden ◽  
...  

1991 ◽  
Vol 30 (22) ◽  
pp. 4166-4176 ◽  
Author(s):  
Saeed. Attar ◽  
Nathaniel W. Alcock ◽  
Graham A. Bowmaker ◽  
James S. Frye ◽  
William H. Bearden ◽  
...  

2005 ◽  
Vol 60 (10) ◽  
pp. 1049-1053 ◽  
Author(s):  
Zeanab Talaei ◽  
Ali Morsali ◽  
Ali R. Mahjoub

Two new ZnII(phen)2 complexes with trichloroacetate and acetate anions, [Zn(phen)2(CCl3COO)- (H2O)](ClO4) and [Zn(phen)2(CH3COO)](ClO4), have been synthesized and characterized by elemental analysis, IR, 1H NMR, 13C NMR spectroscopy. The single crystal X-ray data of these compounds show the Zn atoms to have six-coordinate geometry. From IR spectra and X-ray crystallography it is established that the coordination of the COO− group is different for trichloroacetate and acetate. The former acts as a monodentate whereas the latter acts as a bidentate ligand.


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