New chiral zwitterionic iron hydride complexes with ‘ephosium’ and ‘valphosium’ ligands

1998 ◽  
Vol 566 (1-2) ◽  
pp. 117-123 ◽  
Author(s):  
Jean-Jacques Brunet ◽  
Remi Chauvin ◽  
Jérôme Chiffre ◽  
Sandrine Huguet ◽  
Pascale Leglaye
Keyword(s):  
Hydride Complexes ◽  
Iron Hydride

Synthesis of Iron Hydride Complexes Relevant to Hydrogen Isotope Exchange in Pharmaceuticals

2017 ◽  
Vol 36 (22) ◽  
pp. 4341-4343 ◽  
Author(s):  
Renyuan Pony Yu ◽  
Jonathan M. Darmon ◽  
Scott P. Semproni ◽  
Zoë R. Turner ◽  
Paul J. Chirik
Keyword(s):  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Hydride Complexes ◽  
Hydrogen Isotope Exchange ◽  
Iron Hydride

Pincer Iron Hydride Complexes for Alkene Isomerization: Catalytic Approach to Trisubstituted (Z)-Alkenyl Boronates

ACS Catalysis ◽  
2021 ◽  
pp. 10138-10147
Author(s):  
Songgen Xu ◽  
Peiyu Geng ◽  
Yuling Li ◽  
Guixia Liu ◽  
Lei Zhang ◽  
...  
Keyword(s):  
Hydride Complexes ◽  
Alkene Isomerization ◽  
Iron Hydride

scholarly journals The Reactivity Patterns of Low-Coordinate Iron−Hydride Complexes

2008 ◽  
Vol 130 (20) ◽  
pp. 6624-6638 ◽  
Author(s):  
Ying Yu ◽  
Azwana R. Sadique ◽  
Jeremy M. Smith ◽  
Thomas R. Dugan ◽  
Ryan E. Cowley ◽  
...  
Keyword(s):  
Hydride Complexes ◽  
Iron Hydride

Direct synthesis of dicarbonyl PCP-iron hydride complexes and catalytic dehydrogenative borylation of styrene

2016 ◽  
Vol 45 (27) ◽  
pp. 11101-11108 ◽  
Author(s):  
Shi Jiang ◽  
Samuel Quintero-Duque ◽  
Thierry Roisnel ◽  
Vincent Dorcet ◽  
Mary Grellier ◽  
...  
Keyword(s):  
Efficient Method ◽  
Direct Synthesis ◽  
Iron Carbonyl ◽  
Pincer Complexes ◽  
Hydride Complexes ◽  
Iron Hydride

An efficient method based on the simple metalating reagent Fe(CO)5 leads to the synthesis of cyclometalled PCP iron carbonyl pincer complexes which are active catalytic precursors for the selective dehydrogenative borylation of styrene.

Ruthenium(II) Complexes with N-Heterocyclic Carbene-Phosphine Ligands for the N-Alkylation of Amines with Alcohols

2021 ◽  
Author(s):  
Ming Huang ◽  
Yinwu Li ◽  
Xiao-Bing Lan ◽  
Jiahao Liu ◽  
Cunyuan Zhao ◽  
...  
Keyword(s):  
Metal Hydride ◽  
Phosphine Ligands ◽  
Hydride Complexes ◽  
Borrowing Hydrogen ◽  
Hydrogen Autotransfer

Metal hydride complexes are key intermediates for N-alkylation of amines with alcohols by borrowing hydrogen/hydrogen autotransfer (BH/HA) strategy. Reactivity tuning of metal hydride complexes could adjust the dehydrogenation of alcohols...

scholarly journals Synthesis and Catalytic Reactivity of Cobalt Pincer Nitrosyl Hydride Complexes

2021 ◽  
Author(s):  
Jan Pecak ◽  
Sarah Fleissner ◽  
Luis F. Veiros ◽  
Ernst Pittenauer ◽  
Berthold Stöger ◽  
...  
Keyword(s):  
Hydride Complexes ◽  
Nitrosyl Hydride ◽  
Catalytic Reactivity

Enantiopure dimagnesium(i) and magnesium(ii) hydride complexes incorporating chiral amidinate or β-diketiminate ligands

2021 ◽  
Vol 57 (13) ◽  
pp. 1599-1602
Author(s):  
Caspar N. de Bruin-Dickason ◽  
Christopher A. Rosengarten ◽  
Glen B. Deacon ◽  
Cameron Jones
Keyword(s):  
Hydride Complexes

The first examples of enantiopure, dinuclear magnesium(i) and magnesium(ii) hydride complexes have been kinetically stabilised using bulky chiral β-diketiminate and amidinate ligands (see picture).

Sign in / Sign up

Export Citation Format

Share Document