Synthetic approach towards tetrodotoxin. I. Diels-Alder reaction of α-oximinoethylbenzoquinones with butadiene

1970 ◽  
Vol 11 (59) ◽  
pp. 5127-5128 ◽  
Author(s):  
Y. Kishi ◽  
F. Nakatsubo ◽  
M. Aratani ◽  
T. Goto ◽  
S. Inoue ◽  
...  
1985 ◽  
Vol 16 (34) ◽  
Author(s):  
S. J. BURRELL ◽  
A. E. DEROME ◽  
M. S. EDENBOROUGH ◽  
L. M. HARWOOD ◽  
S. A. LEEMING ◽  
...  

2020 ◽  
Vol 7 (4) ◽  
pp. 215-221
Author(s):  
T. D. Moseev ◽  
A. F. Khasanov ◽  
M. V. Varaksin ◽  
D. S. Kopchuk ◽  
I. S. Kovalev ◽  
...  

A convenient synthetic approach to meso-substituted with 2,2’-bipyridine and 1-(pyridin-2-yl)isoquinoline residues calix[4]arenes is reported. This approach involves the reaction of generated in situ 2-lithio-calix[4]arene with 1,2,4-triazine precursor with the following aromatization of the obtained adduct, and the aza-Diels-Alder reaction of the 1,2,4-triazinyl-substituted calix[4]arene with 2,5-norbornadien or in-situ generated 1,2-dehydrobenzene. The UV/fluorescence response of thus obtained meso-pyridyl-substituted calix[4]arenes to metal cations is studied.


1979 ◽  
Vol 57 (24) ◽  
pp. 3346-3348 ◽  
Author(s):  
Nada Stojanac ◽  
Žarko Stojanac ◽  
Peter S. White ◽  
Zdenek Valenta

Synthesis of compound 16, a ring A seco derivative of quassin (1), is described. The overall strategy consists of manipulations within a rigid system established by a Diels–Alder reaction, followed by unfolding of the molecule. The sequence includes a cyclization of a 1,5-bromoketone with Zn and a selective oxidation of one carbonyl group in a tricyclic diketo diester with peracetic acid.


Tetrahedron ◽  
2005 ◽  
Vol 61 (16) ◽  
pp. 4099-4113 ◽  
Author(s):  
Fedor I. Zubkov ◽  
Ekaterina V. Boltukhina ◽  
Konstantin F. Turchin ◽  
Roman S. Borisov ◽  
Alexey V. Varlamov

Author(s):  
Hideo Nemoto ◽  
Masami Hashimoto ◽  
Hiroshi Kurobe ◽  
Keiichiro Fukumoto ◽  
Tetsuji Kametani

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