Stereoselective nucleophilic addition of chiral lithium enolates to (N-tosyl)imines: enantioselective synthesis of β-aryl-β-amino acid derivatives

2002 ◽  
Vol 43 (17) ◽  
pp. 3209-3212 ◽  
Author(s):  
Zhihua Ma ◽  
Yonghua Zhao ◽  
Nan Jiang ◽  
Xianglin Jin ◽  
Jianbo Wang
Keyword(s):  
Amino Acid ◽  
Nucleophilic Addition ◽  
Enantioselective Synthesis ◽  
Amino Acid Derivatives ◽  
Lithium Enolates

An enantioselective synthesis of β2-amino acid derivatives

2005 ◽  
Vol 16 (7) ◽  
pp. 1309-1319 ◽  
Author(s):  
Jomana Elaridi ◽  
Ali Thaqi ◽  
Andrew Prosser ◽  
W. Roy Jackson ◽  
Andrea J. Robinson
Keyword(s):  
Amino Acid ◽  
Enantioselective Synthesis ◽  
Amino Acid Derivatives

scholarly journals Enantioselective synthesis of α-alkenyl α-amino acids via N–H insertion reactions

2016 ◽  
Vol 7 (2) ◽  
pp. 1104-1108 ◽  
Author(s):  
Jun-Xia Guo ◽  
Ting Zhou ◽  
Bin Xu ◽  
Shou-Fei Zhu ◽  
Qi-Lin Zhou
Keyword(s):  
Amino Acids ◽  
Amino Acid ◽  
Enantioselective Synthesis ◽  
Insertion Reaction ◽  
Amino Acid Derivatives ◽  
Insertion Reactions ◽  
Phosphoric Acids

A new highly enantioselective route to α-alkenyl α-amino acid derivatives using a N–H insertion reaction of vinyldiazoacetates and tert-butyl carbamate cooperatively catalyzed by achiral dirhodium(ii) carboxylates and chiral spiro phosphoric acids was developed.

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