Under the general policy of the national energy-saving emission reduction and sustainable development, the domestic iron and steel enterprises surge in the by-product gas power generation project. There exist many dangerous and harmful factors in by-product steel gas power generation process and which easily caused casualties and the pollution of the environment. The study on risk analysis and evaluation are still relatively dearth about the by-product gas generating process of domestic steel enterprises. The boiler system on a Combined Cycle Power Plant was analyzed and evaluation by ICI/MOND fire and explosion toxicity index method and the method of fault tree analysis, which combined with the actual situation of steel plant Combined Cycle Power Plant. The results show that the combustion system is more dangerous, and the hazard index levels are reduced to lower level after safety compensatory measures except the unit toxicity index higher. The shielding device or gas alarm failure was the main cause of gas poisoning. According to the analysis some feasible measures was put forward. The study has positive guiding significance for risk management and safety administration decision of the Combined Cycle Power Plant.
