Relating the microstructure of enzyme dispersions in organic solvents to their kinetic behavior

1998 ◽  
Vol 22 (3) ◽  
pp. 147-151 ◽  
Author(s):  
Emma Bracey ◽  
Robert A. Stenning ◽  
Brian E. Brooker
1960 ◽  
Vol XXXV (I) ◽  
pp. 34-48 ◽  
Author(s):  
Gerd Ittrich

ABSTRACT A series of organic solvents and phenol derivatives have been examined for the extraction of the pink Kober-colour complex. Optimal results could be achieved for fluorimetry by a solution of 2 % (w/v) p-nitrophenol and 1 % (v/v) ethanol in acetylenetetrabromide, when the green mercury line (546 mμ was used as primary light. The sensitivity, stability and specificity have been improved, compared with the previously described reaction. By changing the sequence of purification steps and by reducing the volume of the urine sample (5 ml) the method for the determination of total oestrogens has been simplified. Approximately 10 determinations can be done within 3–4 hours by one person. Recovery experiments and comparative determinations with a previously described method have been carried out. The excretion of total oestrogens in a complete menstrual cycle is determined with the described method.


2019 ◽  
Author(s):  
Meifeng Wang ◽  
Liyin Zhang ◽  
Yiqun Li ◽  
Liuqun Gu

<p></p>Anomerization of glycosides were rarely performed under basic condition due to lack of efficiency. Here an imidazole promoted anomerization of β-D-glucose pentaacetate was developed; and reaction could proceed in both organic solvents and solid state at room temperature. Although mechanism is not yet clear, this unprecedent mild anomerization in solid state may open a new promising way for stereoseletive anomerization of broad glucosides and materials design in the future..


Author(s):  
L. V. Lukovnikova ◽  
K. I. Stosman ◽  
E. E. Lesiovskaya

Working in contact with nitroglycerine, TNT, RDX, oxygenatom, organic solvents, recorded elevated levels of cortisol in the blood. In contact with metals, their blood levels and cortisol levels did not differ from the average values of the professionally employed population.


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