Effect of the support porosity on the thiophene and dibenzothiophene hydrodesulfurization reactions. Al2O3-TiO2 mixed oxide support

Author(s):  
T. Klimova ◽  
J. Ramírez ◽  
R. Cuevas ◽  
H. González
2017 ◽  
Vol 42 (1) ◽  
pp. 8-13 ◽  
Author(s):  
Yubo Ma ◽  
Zhixian Gao ◽  
Wumanjiang Eli

Rh catalysts supported on Fe2O3, Co3O4 and Fe2O3–Co3O4 mixed oxide were prepared by the co-precipitation method. The effect of the support on the performance of the Rh catalysts for the hydroformylation of dicyclopentadiene was investigated using X-ray photoelectron spectroscopy, H2-temperature-programmed reduction, H2-temperature-programmed desorption and Brunauer–Emmett–Teller analysis techniques. The results indicated that the Fe2O3–Co3O4 supported catalyst had a higher dispersion of Rh and thus more Rh+ sites. As a result, the Fe2O3–Co3O4 supported Rh catalyst exhibited higher activity compared with counterparts supported on Fe2O3 and Co3O4.


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