Structure characteristics and valence state study for La1−xNaxTiO3 synthesized under high-pressure and high-temperature conditions

2000 ◽  
Vol 42 (1-2) ◽  
pp. 1-6 ◽  
Author(s):  
Ji-Peng Miao ◽  
Li-Ping Li ◽  
Hong-Jian Liu ◽  
Da-Peng Xu ◽  
Zhe Lu ◽  
...  
2005 ◽  
Vol 387 (1-2) ◽  
pp. 287-291 ◽  
Author(s):  
Ji-Peng Miao ◽  
Zhe Lü ◽  
Li-Ping Li ◽  
Fan-Long Ning ◽  
Zhi-Guo Liu ◽  
...  

1998 ◽  
Vol 278-281 ◽  
pp. 612-617 ◽  
Author(s):  
Bogdan F. Palosz ◽  
Svetlana Stelmakh ◽  
Stanislaw Gierlotka ◽  
M. Aloszyna ◽  
Roman Pielaszek ◽  
...  

2005 ◽  
Vol 71 (704) ◽  
pp. 1183-1189 ◽  
Author(s):  
Hiroyuki NISHIDA ◽  
Takuma OGAWA ◽  
Eiji WAKISAKA ◽  
Takeshi TACHIBANA

2004 ◽  
Vol 59 (2) ◽  
pp. 202-215 ◽  
Author(s):  
Holger Emme ◽  
Tanja Nikelski ◽  
Thomas Schleid ◽  
Rainer Pöttgen ◽  
Manfred Heinrich Möller ◽  
...  

The new orthorhombic meta-oxoborates RE(BO2)3 (≡REB3O6) (RE = Dy-Lu) have been synthesized under high-pressure and high-temperature conditions in a Walker-type multianvil apparatus at 7.5 GPa and 1100 °C. They are isotypic to the known ambient pressure phase Tb(BO2)3, space group Pnma. In contrast to Dy(BO2)3, which was also obtained in small amounts under high-temperature conditions, the preparation of the higher orthorhombic homologues RE(BO2)3 (RE = Ho-Lu) was only possible using high-pressure. The meta-oxoborates RE(BO2)3 (RE = Dy-Er) were synthesized as pure products, whereas the orthorhombic phases with RE = Tm-Lu were only obtained as byproducts. With the exception of Yb(BO2)3 it was possible to establish single crystal data for all compounds. The results of temperature-resolved in-situ powder-diffraction measurements, DTA, IR-spectroscopic investigations, and magnetic properties are also presented.


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